Chapter 6应化概要1.pptVIP

化 学 反 应 工 程 Part (b) Solution. Drawing slopes and diagonals according to the method of maximization of rectangles we end up with Fig. E6.3b. For 1 tank For 2 tanks 化 学 反 应 工 程 Figure E6.3b One and two mixed flow reactors in series. 化 学 反 应 工 程 Part (c) Solution. Following the reasoning(推理, 论证) in this chapter we should use a mixed flow reactor followed by a plug flow reactor. So with Fig. E6.3c we find Note which scheme (a) or (b) or (c) gives the smallest size of reactors. 化 学 反 应 工 程 Figure E6.3c Arrangement with smallest volume. 化 学 反 应 工 程 6.3 RECYCLE REACTOR In certain situations it is found to be advantageous(有利的) to divide the product stream from a plug flow reactor and return a portion of it to the entrance of the reactor. Let the recycle ratio R be defined as R = (15) This recycle ratio can be made to vary from zero to infinity. Reflection suggests that as the recycle ratio is raised the behavior shifts from plug flow (R=0) to mixed flow (R= ∞). Thus, recycling provides a means for obtaining various degrees of backmixing with a plug flow reactor. 化 学 反 应 工 程 Consider a recycle reactor with no’menclature(命名法,术语) as shown in Fig.6.13. Across the reactor itself Eq.5.18 for plug flow gives (16) Where would be the feed rate of A if the stream entering the reactor (fresh feed plus recycle) were unconverted. Since and are not known directly, they must be written in terms of known quantities before Eq.16 can be used. Let us now do this. 化 学 反 应 工 程 Figure 6.13 Nomenclature for the recycle reactor. 化 学 反 应 工 程 The flow entering the reactor includes both fresh feed and the recycle stream. Measuring the flow split(辟开,分开) at point L (point K will not do if ) we then have = (A which would enter in an unconverted recycle stream) + (A entering in fresh feed) = R (R+1) (17) Now to the evaluation of : from Eq. 4.5 we may write (18) 化 学 反 应 工 程 Because the pressure is taken to be constant, the stre