球形钴粉的制备及其在超细晶粒硬质合金中的应用 - 中国有色金属学报.PDFVIP

第 18 卷第 2 期 中国有色金属学报 2008 年 2 月 Vol.18 No.2 The Chinese Journal of Nonferrous Metals Feb. 2008 文章编号：1004-0609(2008)02-0209-06 球形钴粉的制备及其在超细晶粒硬质合金中的应用 1, 2 1 1 谭兴龙 ，易茂中 ，罗崇玲 (1. 中南大学 粉末冶金国家重点实验室，长沙 410083 ； 2. 湖南顶立科技有限公司，长沙 410111) 摘 要：以碳酸钴为原料，采用氢气还原法在带式无舟皿连续还原炉中制备超细球形钴粉。考察还原温度和还原 时间对钴粉粒度的影响。结果表明，在420~460 ℃还原 180 min 左右，可以制备费氏粒度为 0.9 μm 左右的超细球 形钴粉。采用二氧化碳气体钝化处理技术降低了钴粉的氧含量。采用制备的钴粉为超细晶粒硬质合金的粘结剂， 用低压烧结工艺制备出钴相高度分散、晶粒均匀的超细晶粒YG10 硬质合金。其晶粒度为 0.4 μm ，矫顽磁力达 38.0 kA/m ，硬度大于 93.0 HRA，抗弯强度高于 3 700 MPa 。 关键词：超细球形钴粉；气体钝化；超细晶粒硬质合金 中图分类号：TF 76.133 文献标识码：A Preparation of spherical cobalt powder and its application in ultra-fine cemented carbides TAN Xing-long1, 2 1 1 , YI Mao-zhong , LUO Chong-ling (1. State Key Laboratory of Powder Metallurgy, Central South University, Changsha 410083, China; 2. Hunan Denli Technology Co. Ltd, Changsha 410111, China) Abstract: Ultra-fine cobalt powder was prepared by the reduction of carbonate using a belt continuous boat-less reducing furnace in hydrogen. The influences of reduction temperature and time on the particle size of cobalt powder were studied. Ultra-fine spherical cobalt powder with particle size of around 0.9 μm was prepared at 420−460 ℃for 180 min. The influence of CO2 passivation treatment on the oxygen content of cobalt powder was discussed. Ultra-fine WC-10Co cemented carbides were prepared