基于强抗积碳的co2 重整镍基催化剂的研究进展 - 硅酸盐学报.pdf

第 44 卷第 4 期 硅 酸 盐 学 报 Vol. 44 ，No. 4 2 0 1 6 年 4 月 JOURNAL OF THE CHINESE CERAMIC SOCIETY April ，2016 DOI ：10.14062/j.issn.0454-5648.2016.04.25 综 合 评 述 基于强抗积碳的CO 重整镍基催化剂的研究进展 2 张盼艺，郭 芳，许俊强，陈 志，李 军 (重庆理工大学化学化工学院，重庆 400054) 摘 要：针对甲烷－二氧化碳重整用 Ni 基催化剂易于高温积碳失活问题，系统总结了重整催化剂的抗积碳性能的影响因素， 分析了载体的载氧性、表面酸碱性和载体孔道结构与抗积碳性之间的关系，探讨了助剂改性催化剂表面酸碱性、金属与载体 相互作用和活性组分的分散度对抗积碳性的影响，揭示了特殊场物理技术改性的催化剂表面活性组分 Ni 粒子尺寸和分散度 与催化剂抗积碳性之间的关联度，阐释了 Ni 基催化剂积碳的原因，提出了改善重整催化剂的抗积碳性的具体方法和措施， 并展望了强抗积碳的重整催化剂的发展趋势。 关键词：二氧化碳重整甲烷；镍基催化剂；抗积碳 中图分类号：TQ174.75 文献标志码：A 文章编号：0454–5648(2016)04–0620–07 网络出版时间：2016–03–18 16:07:25 网络出版地址：/kcms/detail/11.2310.TQ1607.025.html Progress of Coke Resistant Ability Research of Ni-based Catalysts for CO2 Reforming of Methane ZHANG Panyi, GUO Fang, XU Junqiang , CHEN Zhi, LI Jun (School of Chemistry and Chemical Engineering, Chongqing University of Technology, Chongqing 400054, China) Abstract: Carbon deposition is a key problem for carbon dioxide reforming of methane with the non-noble metal Ni based catalysts at high temperature. The performance of carbon deposition resistance of reforming catalysts was summarized. The relationships among carbon deposition resistance and oxygen carrying ability of supports, surface acidity as well as carrier structures were presented. The effects of surface acidity, metal support interaction and active component dispersion of various types of promoters modified catalysts on the carbon deposition resistance were analyzed. The relationship betwe