电化学沉积法制备巨孔结构氧化锰电极及其电化学特性研究.docVIP

中文摘要 本研究利用單一分佈之聚苯乙烯球形成模板，並以陽極沉積法製備巨孔結構之氧化錳電極，探討結構對於其電化學特性的影響。以場發射電子顯微鏡(FE-SEM)觀察電極的表面型態變化，並以低掠角的X-光繞射(GA-XRD)儀分析其結晶結構。在電極的電化學特性分析上，以1 M Na2SO4溶液作為電解液進行循環伏安(CV)、恆定電流充放電以及循環壽命等測試。SEM圖顯示沉積之二氧化錳薄膜具有奈米線狀之結構，其孔洞型態依製備方式不同，可形成巨孔型、中空型以及導電巨孔型等。GA-XRD分析結果顯示，陽極沉積法製備之氧化錳薄膜經熱處理300oC後為MnO2結晶結構。 由於巨孔結構氧化錳電極可增加其比表面積的利用率，並有利於電解質進入和離子的遷移，故對其電化學反應有正面的影響。此外，於聚苯乙烯球表面電泳沉積一層氧化鎳薄膜，可增加氧化錳薄膜電極的導電性，使電極的電容特性明顯提升。電化學分析結果顯示，在掃描速率10 mVs-1下，巨孔型氧化錳電極比電容值可達288 Fg-1；中空型電極比電容值為504 Fg-1；導電巨孔型電極比電容值可達472 Fg-1。相較於二氧化錳薄膜電極比電容值257 Fg-1，中空型與導電巨孔型二氧化錳電極之比電容值提升約一倍。 英文摘要 In this study, the monodispersed polystyrene (PS) spheres are used as the template in anodic electrodeposition to form macroporous manganese oxide electrode. The effects of electrode’s structure on the electrochemical behavior are investigated. Field-emission Scanning electron microscope (FE-SEM) and glancing angle X-ray diffraction (GA-XRD) were used to identify the film surface morphology and crystal structure. The electrochemical performances of the films are characterized by means of cyclic voltammetry, galvanostatic charge/discharge and cycle-life test in 1 M Na2SO4 electrolyte. The SEM image shows that the morphology of manganese oxide film is composed of nanowires. The macroporous, hollow and conductive porous MnO2 electrodes can be obtained by tuning the fabricating process. GA-XRD analysis shows that the crystal structure of the film annealed at 300oC is MnO2 . Porous film structure can enhance significantly the specific surface area and the utilization of MnO2 due to the facilitation of electrolyte penetration and migration through film. Hence, the porous structure has positive effects on the capacitive behavior of film. In addition, depositing the conductive NiO film onto the PS sphere by electrophoretic deposition (EPD) can enhance the capacitive behavior of MnO2 film possibly due to an increased electrical conductivity of film. The electrochemical results show that the specific capacitance of the macroporous, hollow and conduct