镀镍液中铁杂质的影响及处理方法.pdfVIP

408601 ρ(Fe2+) 200 mg/L WZ-Fe 2+ Fe KMnO H O 4 2 2 2 TQ153.12 B 2. 1 1004 – 227X (2007) 05 – 0031 – 02 Influence and treatment methods of iron impurity in nickel plating bath PU De-li, GONG Ping Abstract: The producing ways of iron impurity in nickel plating bath and its influence on quality of nickel deposit were analyzed. Methods for treating iron impurity in bath pH = 3.8 ~ 4.5 pH = 2.5 ~ 3 pH = 3.8 were introduced in different conditions. Iron ion is ~ 4.5 eliminated by adding a ferric removal agent of WZ-Fe when 40 °C ρ(Fe2+) 200 mg/L; electrolysis method at small current density is used in common maintenance; oxidation process 2. 2 using KMnO or H O is preferred at high mass 4 2+ 2 2 Fe2+ concentration of Fe . Keywords: nickel plating; bath maintenance; iron impurity; Fe(OH)2 pH 4.0 treatment Fe2+ First-author’s address: Jianfeng Mechanical Production Fe2+ 1 644 mg/LFe2+ Factory of China Nuclear Industry Jianfeng General 0.5 mmol/L Chemical Factory, Chongqing 408601, China Fe3+ Fe(OH)3 291 K: 4 × 10-38 pH = 4.0 Fe3+ Fe3+ 1 Fe(OH)3 Fe2+Fe3+