钇钡铜氧超导膜溶液法沉积过程中氟化钡中间相的热力学分析.pdfVIP

Material Sciences 材料科学, 2017, 7(2), 232-237 Published Online March 2017 in Hans. /journal/ms /10.12677/ms.2017.72030 Thermodynamics Analysis on BaF2 Intermediate Phase in Solution-Derived YBCO Superconducting Film Deposition 1 1 2* 1 1 3 Hongyuan Lu , Feng Feng , Wei Wu , Xiangsong Zhang , Linli Wang , Timing Qu , Shengjun Zhai4, Pingfa Feng1 1 Division of Advanced Manufacturing, Graduate School at Shenzhen, Tsinghua University, Shenzhen Guangdong 2 Department of Electrical Engineering, Shanghai Jiao Tong University, Shanghai 3 Department of Mechanical Engineering, Tsinghua University, Beijing 4 Beijing Eastforce Superconducting Technology Co., Ltd., Beijing th th st Received: Mar. 19 , 2017; accepted: Mar. 28 , 2017; published: Mar. 31 , 2017 Abstract In the YBa Cu O (YBCO) high temperature superconducting thin film fabrication via the chemi- 2 3 7-δ cal solution deposition method, BaF2 is an important intermediate phase during heat treatment. In this paper, BaF2 thermodynamics stability was analyzed through calculating the standard Gibbs free energy change (ΔGT) of the reactions related to other intermediate phases within the temper- ature range of 700 - 1000 K. Two thermodynamics methods, the Gibbs free energy function me- thod and standard formation molar Gibbs free energy method, were utilized to obtain the ΔGT values. This study confirms the formation priority of BaF2 relative to other mesophase at high temperatures while the possibility of BaCO3 formation was found at 700 K