海带基微孔介孔复合多级孔纳米炭的制备及电化学性能研究.pdfVIP

Hans Journal of Nanotechnology 纳米技术, 2017, 7(1), 11-20 Published Online February 2017 in Hans. /journal/nat /10.12677/nat.2017.71002 Study on Synthesis and Electrochemical Performance of Micro-Mesoporous Nano-Carbon Derived from Seaweed as Electrode Material for Supercapacitors 1 1* 1 1 2* Feixu Zong , Chao Pan , Jingyi Gao , Zhaohui Gao , Li Dong 1 College of Science, Dalian Ocean University, Dalian Liaoning 2 College of Science, Dalian Nationalities University, Dalian Liaoning st th th Received: Jan. 21 , 2017; accepted: Feb. 17 , 2017; published: Feb. 20 , 2017 Abstract The fresh seaweed is used as a natural precursor to prepare micro-mesoporous nano-carbon ma- terials. The micro-mesoporous carbon was synthesized by washing, acidification and carboniza- tion at different temperatures. The synthesized hierarchical micro-mesoporous carbon was cha- racterized by SEM, TEM, BET, Raman and electrochemical measurement techniques. The results confirmed that such micro-mesoporous carbon possessed higher electrochemical capacitance than commercial active carbon. The porous carbons activated at 800˚Cpresent high surface area (up to 1703.97 m2/g) and high specific capacitance of 200 F/g at a current density of 5 A/g, and superior cycling stability in a 4 M KOH aqueous solution. The good capacitive performance can be ascribed to the high specific surface area and well-controlled micro- and mesoporosity. Keywords Seaweed, Micro-Mesoporous Nano-Carbon, Supercapacitor, Electrochemical Performance 海带基微孔/介孔复合多级孔纳米炭的制备及电 化学性能研究 1 1* 1