傅里叶变换_红外光谱法快速测定面粉中滑石粉.pdfVIP

, ( , 110015) : 提出了应用衰减全反射( AT R) 傅里叶变换红外光谱( FTIRS) 法快速检测面粉中混入 的滑 粉, 测定中采用中红外检测器根据滑 粉的标准红外光谱图并为避免面粉的吸收干扰, 选 择滑 粉在 3 674. 96 cm- 1 及668. 16 cm- 1两处的特征吸收峰作为判定面粉中是否含有滑 粉的 依据, 并且其吸收强度随滑 粉含量的增加而增加由于面粉中滑 粉质量分数低于0. 5% 和 0. 2% 时, 分别在上述两吸收峰波长处已不呈现吸收, 方法中将1%( 质量分数) 作为滑 粉的检出 限此外, 根据吸收峰的吸收强度可估算出滑 粉的含量方法中选用的主要仪器工作条件为: 扫描范围为4 000~ 650 cm- 1 ; 分辨率为8 cm- 1; 扫描信号累加次数为32; 衰减全反射压 力常数为100 : 傅里叶变换红外光谱法; 衰减全反射; 面粉; 滑 粉 : O657. 33 : A : 2011) RapidDetermination of Talc Powder in Flour by FTIRS ZHAO Yanhua, HA Xu ( L iaoning Pr ov incial R esearch Center of Eng ineer ing Technology f or Establishment of Stand ar diz ation Sy stem, L iaoning Pr ov incial Research I ns titute of A naly tical Science , S heny ang 110015, China Abstract: FTIRS wit attenuated tot al reflection ( ATR) was applied to t e rapid determination of talc powder illicitly mixed into flour. Medium IR det ector was used in t e analysis. By referring t e standard IR spectra and considering t e absorption interference of flour, 2 of t e 3 IR absorpt ion peaks of talc pow der, i. e. , t e peaks at 3 674. 96 cm- 1 and 668. 16 cm- 1 , w ere selected as t e c aract eristic absorpt ion peaks to determine w et er talc powder w as present or not in t e sample. It was s ow n t at w en t e content ( w %) of talc pow der in flour w as low er t an 0. 5% or 0. 2% , no absorption was f ound in t e spect ra at t e 2 wavebands respectively. Value of 1% ( w %) w as taken as t e detection limit. In addition, magnitude of absorption intensit y at bot t e w avebands w as increased w it t e increase of amounts of talc pow der present, ence t e content of talc powder in samples of f lour could be estimated. Working condit ions of t e instrument