Reactions of Alkoxysulfonium Salts with Alkoxides,还原砜与亚砜得硫醚.pdf

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Reactions of Alkoxysulfonium Salts with Alkoxides,还原砜与亚砜得硫醚.pdf

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Reactions of Alkoxysulfonium Salts with Alkoxides,还原砜与亚砜得硫醚

1926 JOHNSON AND PHILLIPS VOL.32 The second fraction of the chloroform eluate contained the de- mp 186-188.5 (sinters a t 180); ultraviolet 230 mp sired product, which was recrystallized from ligroin to give (1.O (sh) (log e 4.08), 240 (sh) (4.00), and 282 (4.31). g, 2.5 mmoles, 50%) of 37 as colorless crystals, mp 35-36. An Ana2. Calcd for CNHWN~O$~:C, 66.27; H, 8.37; N, 7.73. analytical sample was prepared by further recrystallization from Found: C, 66.59; H, 8.47; N, 7.84. ligroin: mp 35-36; ultraviolet XEzEtoH237 mfi (log 6 4.07) and 287 (4.09); nmr singlet I 6.12, OCHs) and complex multi- Registry No.- 10351-64-1; 13, 5566-47-2; 14, plet centered a t 7 8.7. 10351-66-3; 15, 10351-67-4; 16, 10351-68-5; 17, Anal. Calcd for C~H3404S:C, 66.98; H, 8.69. Found: C, 67.16; H, 8.63. 10378-07-1; 18, 10351-69-6; 19, 10351-70-9; 20, 4-Dodecanethiophthalic acid was prepared by the hydrolysis 10351-71-0; 21, 10351-72-1; 22, 10351-73-2; 23, of dimethyl ester 37with hot aqueous alkali followed by acidifica- 10351-74-3;27, 582-60-5;28, 10351-75-4;29, 10351- tion. Recrystallization from benzene yielded crystals melting 76-5;hydrochloride of 29, 10351-77-6;30, 10351-78-7; a t 11~110.5. 31, 10351-79-8;32, 10351-80-1;33, 7153-23-3; 34, Anal. Calcd for (004S: C, 65.55; H, 8.25. Found: C, 65.54; H, 8.19.