不同生物质制备的生物炭对菲的吸附特性研究.pdfVIP

环境工程 166 Environmental Engineering 不同生物质制备的生物炭对菲的吸附特性研究* 张晗林宁黄仁龙舒月红 (华南师范大学化学与环境学院，广州 510006) 摘要:以不同来源的生物质(荔枝树枝、小麦和水稻秸轩)为原料，在限氧条件下制备生物炭，对其进行表征，并进行吸 附实验研究生物炭对菲的吸附特性。结果表明:生物炭的结构和理化性质随着生物质来源和热解温度的不同而呈现 出明显的差异;荔枝树枝生物炭对菲的吸附能力 ( q.) 和吸附亲和力 (Koo) 要明显大于小麦秸轩和水稻秸轩制备所得的 生物炭，说明木本植物来源的生物炭与草本植物来源的生物炭在结构性质上有着明显的差异;不同温度(300 ， 400 ， 500 ,600 C )制备的荔枝树枝生物炭对菲的吸附研究表明，随着热解温度的升高，生物炭对菲的吸附能力(q.) 和吸附 亲和力 (K ， ) 明显增强，吸附等温线的线性程度降低。生物炭吸附菲的可能机制有疏水效应、孔隙填充效应以及节 -τ o 共辄反应等。 关键词:生物质来源;生物炭;热解温度;菲;吸附 DOI:I0.13205/j. hjgc.201610034 SORPTION OF PHENANTHRENE ON BIOCHARS PRODUCED FROM DIFFERENT BI。如IASS 岛1ATERIALS ZHANG Han , LIN Ning , HUANG Ren-long , SHU Yue-hong (School of Chemistry and Environment , South China Normal University , Guangzhou 510006 , China) Abstract: Biochar were synthesized by different biomass materials (litchi branches , wheat straw and rice straw) under limited oxygen , and were characterized. Sorption isotherms of phenanthrene were examined to evaluate its sorption behavior. The results showed that the structure and physical-chemical properties of biochars were significantly influenced by biomass materials and pyrolysis temperature. The sorption capac即( q,) and sorption affinity (Koo) of phenanthrene by litchi biochar were higher compared with the other two kinds of biochar in this study , which demonstrated that biochar produced from wood material was much different from those produced from herbal materials. With the increase of pyrolysis temperatures , sorption capac向 (q，) and sorption affinity (Koo) of phenanthrene by litchi biochar inc