锰基高强度高塑性高阻尼记忆合金研究.docVIP

锰基高强度高塑性高阻尼形状记忆合金研究 周宏雷 董元源 (江阴职业技术学院机电工程系， 江苏，江阴，邮编：214405) [摘要]：用磁悬浮熔炼、测定试样形状记忆效应（SME）和双程形状记忆效应（TWSME）、金相法、示差量热分析（DSC）、断口SEM观察和自由震动波衰减曲线等方法研究了高强度高塑性高阻尼的Mn基形状记忆合金的记忆特性，以及Cu、Ni、Fe、Cr、Ti、N等合金元素的作用。结果表明，Cu溶入愈多，合金的形状记忆效应愈高；适当的时效热处理可强化合金，提高SME；含Ti、N元素的合金3（Mn-Cu50-Ni5-Cr0.5-Fe1-Ti1-N0.1）有最好的SME，回复率达73%。所研究的合金都有明显的双程形状记忆效应。合金3的TWSME形状恢复率达21%。淬火状态的合金有高的塑性，延伸率达25%，表示有极高的加工工艺性，并有良好的阻尼抗震能力。淬火时效状态的合金有高的强度极限，尤其是高的屈服极限（σs=320-475MPa），适当的塑性（δ=4.2-5%以上），预示合金有较高的断裂韧性K1c。合金元素还能提高所研究合金的抗氧化和抗腐蚀能力。 关键词：锰基高强度高塑性高阻尼记忆合金；形状记忆效应；形状回复率；时效热处理；合金元素。 中图分类号：TG139.6 A Study on High Strength, High Plasticity and High Damping Shape Memory Alloys Based on Mn ZHOU Hong-lei DONG Yuan-yuan (Department of Mechanic ＆ Electronic Engineering, Jiangyin Polytechnic College，Jiangyin214405,Jiangsu,China) Abstract: The shape memory alloys with high strength high plasticity and high damping based on Mn containing elements Cu、Ni、Cr、Fe、Ti、N and the effects of alloy elements on shape memory characterization, tensile properties and temper heat treatment have been investigated，using magnetic suspension melting, determining shape memory effect（SME）, metallography, DSC of specimen, SEM of fracture surface and free decay curve of vibration wave. The results show that the more element Cu enter Mn bulk， the more shape memory effect(SME) is; temper heat treatment improves the SME of tested alloys，but raises the martensite transformation temperature; alloy 3，containing elements Ti and Ni possesses the best SME among them， the shape recovery rate is up to 73%. All the tested alloys have excellent two-way SME， the TWSME of alloy 3（Mn-Cu50-Ni5-Cr0.5-Fe1-Ti1-N0.1） is up to 21%. Alloy in quenching state has high plasticity， good workability. Alloys in quenching and tempering state have higher strength，especially high yield strength(σs=320～475MPa) and suitable plasticity(δ≥4.2～5%)，so it should have higher fracture toughness K1c Tested alloys possess good damping ability and good anti-oxidation and resistant corrosion chara