应用八级杆碰撞反应池技术电感耦合等离子体质谱法测定化妆品中17种有害元素.pdfVIP

Vol. 11 No.6 Feb.2011 科学技术与工穗 第 11 卷第6 期 2011 年2 月 1671--1815(2011)6-1381-05 Science Technology and Engineering @ 2011 Sci. Tech. Engn侈 应用八级忏碰撞反应池技术电感搞合等离子 体质谱法测定化妆品中 17 种有害元素 2 于宙l 江志月tl ·张帅2 李宗芮2 傅余强2 李群l (青岛大学应用化学系I 青岛 266071; 山东出入境检验检疫局2 ，青岛篇附2) 摘要 样品在硝酸及少量双氧水中，采用微波消解前处理，应用碰撞反应池技术电感稿合等离子体质谱法同时测定化妆品 中敏、棚、锡、铁、铭、钵、钟、砸、银、铺、锡、锡、琪、钦、蒙、钝和铅等 17 种有害元素，通过样品前处理和电感精合等离子体质谱法 测定时条件的选择，消除了质谱子扰和基体效应，各元素的检出限(35) 在 O. ∞1 - O. 121 mg • kg 嗣 1 ，仪器精密度(n= l1) 在 0.64% 呻 8.35% 之间，方法精密度(n= l1) 在1. 52% -8.46% 之间，17 种元素的加标回收率在87.28% 嗣 119.06% 范圈内。 关锦词 电感稿合等离子体质谱法 化妆品 有存元素 中回法分提号 T耶53; 文献标志间 B In recent yea盼， the security of cosmetics became um , neodymium and so on (2). The standard inspec- the new hotspots that attract public s attention. The tion method prescribed by the state w由 cockamamie. cosmetics adding raw material containing hannfuI ele幽 In daily work , it only determined portions of harmful ments such 幽 mercu町， lead in manufacture process ele跚跚 at on忱 and the test cycle was long. In Chi- would cause harm to human body , such 剧 mercury nese cosmetics hygiene standards the digestion methods would catalyze skins , affected the central nervous sys- of cosmetics contained dry cineration , wet digestion tem , made a per勤on appear the symptom of memory de- and microwave digestion. The dry method of digestive cline and insomnia; Lead would result in the neur翩翩 must use exorbitant equipment , i怡 working cycle was thenia and affect the digest