循环伏安法测定聚苯并咪唑膜电解质甲醇透过率.pdfVIP

第36 卷第5 期 东北大学学报(自然科学版) Vo 1. 36 ,No.5 2015 年 5 月 Joumal of Northeastem University (Natural Science) May 2015 doi: 10. 3969/j. issn. 1005 - 3026. 2015. 05. 032 循环伏安法测定聚苯并咪睡膜电解质甲醇透过率 杨景帅，李雪源，徐一鑫，何荣桓 (东北大学理学院，辽宁沈阳 110819) 摘 要:研究建立了电化学循环伏安法(CV) 测定磷酸掺杂聚苯并眯瞠(PBI) 膜甲醉透过率的方法.以 磷酸熔液为电解质，在扫描电压范围 -0.2 - 1. 2 V 和扫描速度 IωmV/s 的条件下测试了不同磷酸掺杂水平 PBI 膜的甲醇透过率.研究表明，根据膜样品酸掺杂水平选择磷酸电解质溶液的浓度可使待测 PBI 膜的酸掺 8 杂水平在测定过程中保持不变，进而保障结果的准确性和可靠性;与纯 PBI 膜的甲醇透过率(1. 34x lO- 2 cm /s) 相比，磷酸掺杂 PBI 膜的甲醇透过率有所增加，当 PBI 膜的酸掺杂水平为2.5 - 3.2 时，膜的甲醇透过 8 8 2 率为 3.2 X 10- -14 X 10- cm /s. 关键词:甲醇透过率;循环伏安法;聚苯并咪瞠膜;磷酸;燃料电池 中图分类号: TP 0646. 542 文献标志码:A 文章编号: 1005 -3026(2015)05 -0757-04 Measurement of the Methanol Permeability of Polybenzimidazole Membrane Electrolytes with Cyclic Voltammetry YANG ling-shuai , LI Xue-yuαn ， XU Yi-xin , HE Rong-huαn ( School of Sciences , Northeastem University , Shenyang 110819 , China. Corresponding author: HE Rong-huan , professor ,E-mail: herh@mai 1. neu.edu.cn ) Abstract: A method for measuring the methanol permeability of phosphoric acid doped polybenzirnidazole (PBI) membranes was developed by using cyclic voltammetry (CV). The methanol permeability of PA doped PBI membranes at different acid doping levels was investigated under a voltage range of - O. 2 - 1. 2 V and at a potential sweep rate of 100 m V / s using phosphoric acid solutions as electrolytes. The results indicated that using the PA solution with a suitable concentration as the electr