微回流分光光度法测定水中化学需氧量的研究.pdfVIP

环境科技 第 26 卷第2 期 Vol.26 No.2 2013 年 4 月 Environmental Science and Technology Apr.2013 微回流分光光度法测定水中化学需氧量的研究 陈丽琼 1 ，胡勇2 (1.云南省环境监测中Ü 站， 云南 昆明 白∞34; 2. 西南林业大学， 云南 昆明 650224) 摘 要: 采用美国哈希公司生产的 COD 测定仪和加热器，用微回流管封闭回流消解水样，对水中化学需氧量的测 定方法进行研究。实验结果显示，该方法的准确度和精密度较高，测定结果的相对标准偏差在 0.33% - 2.201毛之间，变 异系数在 0.491毛- 2.54%之间;检出限较低，采用质量浓度测定范围为 3 - 150 mg/L的试剂测定水样，检出限为 3 mg/L;对标准样品及具有代表性的水样测定，结果与国标回流法的测定结果相比没有显著性差异，且结果的相对偏差 均在质控要求范围内。 关键词: 水质; 微回流; 分光光皮法; 化学需氧量 中图分类号: X8 文献标识码:A 文章编号: 1674-4829(2013)02-∞55-03 Study on the Chemical Oxygen Demand of Water Determined by Micro-ret1ux Spectrophotometry 1 CHEN Li-qiong , HU Yong 2 (1. Yunnan Environmental Monitoring Center, Kunming 65∞34， China; 2. Southwest Forestry University , Kunming 650224, China) Abstract: In this paper, COD tester ,heater and micro-reflux tubes produced hy American HACH company were used to digest water samples closely, to study the method of detennining Chemical Oxygen Demand. The experimental results showed tbat the accuracy and precision were higher, the relative standard deviations we陀 0.3 3% - 2.209毛， and the coefficients of variations were 0.491毛- 2.541毛. The detection limit was 3mg/L which was lower, when the determination range of reagent were 3 -150mg/L. The results of standard samples and representative water samples determined by micro -reflux spectrophotometry had no significant differences wÏth the results determined hy national standard-reflux method. The relative deviations of the results are all within the