溴酸钾氧化孔雀石绿和甲基红的褪色光度法测定NO2-的研究.pdfVIP

ofAnhui 安徽农业科学，Journal Agn．Sci．2013，41(28)：11264—11265 责任编辑刘月娟责任校对卢瑶 溴酸钾氧化孔雀石绿和甲基红的褪色光度法测定N02一的研究 柴红梅，白亮，王雷，予J、雪花 (延安大学化学与化丁学院，陕西省化学反应工程重点实验室，陕西延安716000) 摘要[目的]建立一种新的测定痕量亚硝酸根的方法。[方法]在磷酸介质中以CTMAB为活化剂，利用亚硝酸根对溴酸钾氧化孔雀石 绿和甲基红的褪色反应有催化作用，通过测定520和612nm处催化和非催化体系吸光度的变化值，建立双波长双指示剂催化动力学光 3 度法测定痕量亚硝酸根的新方法。[结果]该方法的线性范围为o～0．16彬IIll，检出限为0．004wr／Ⅱll。[结论】将该方法用于榨菜试 样中亚硝酸根的测定．结果满意。 关键词催化动力学；双波长；双指示剂；孔雀石绿；甲基红；亚硝酸根 中图分类号S181．3文献标识码A 文章编号0517—66ll(2013)28—11264—02 Kinetic DeterminationofTraceNitriteBasedonOxidativeDiscolorationMalachiteGreenandMeth． CatalyticSpectrophotometric of RedPotassiumBromate yl by CHAI etal ChemicalReaction of of Hong·mei (ShaanxiKeyLaboratory Engineering，YananUniversity．Department cal Engineering．Yan’an．Shaanxi716000) Abstract newmethodiS forthedeterminationoftrace Anew anddual—indicator Objective]A developed nitrite．『Method1 dual—wavelength kinetic methodwas forthedeterminationoftracenitrite．Itwasbasedon山e effectofnitriteon catalytic spectrophotormetricdeveloped eatalytic theoxidationofMalachiteGreenand bromate red inthemediumof CTMABasactivator．Theofab． Methylbypotassium H，P0。with changes sorbancewit}l and weremeasuredat520and612nm ResultlThelinear ofthemethodWas catalyticuncatalyticsystems respectively．f range andthedetectionlimitwas0．004 methodhasbeen tothedeterminationof 0—0．16斗g／ml 3斗g／m1．[Conclusion]，nleappliedsatisfactorily in nitrite picklessamples． wordsKinetic Key spectroph