树脂分离-原子吸收法测定涉水产品及饮用水中六价铬.pdfVIP

中国卫生检验杂志2007年12月第17卷第l2期 Chinese Journal of Health Laboratory Technology，Dec 2007；Vol 17 No 12 2225 【化学测定方法】 树脂分离一原子吸收法测定涉水产品及饮用水中六价铬 商博东，张维，陆珩，张明月 (天津市疾病预防控制中心，天津 300011) [摘要] 目的：建立石墨炉原子吸收法测定涉水产品及饮用水中六价铬含量。方法：采用强酸性阳离子树脂柱对样品进 行前处理，并以磷酸二氢铵为基体改进剂，采用石墨炉原子吸收测定六价铬含量。结果：强酸性阳离子树脂柱可有效去 除三价铬及其它共存离子，10 g／L磷酸二氢铵可使测定的精密度和稳定性得到改善，并减少基体干扰。铬浓度在0～ 10．00 g／L范围内，回归方程为Y=0．0539X+0．006，r=0．9993，具有良好的线性关系；方法的检出限为0．02 g／L，相 对标准偏差为2．84％～7．14％，方法回收率为89％～108％，该法与国标化学法结果对比无显著性差异。结论：方法精密 准确，快捷灵敏，抗干扰能力强，便于推广。 [关键词] 石墨炉原子吸收；树脂；六价铬 [中图分类号] 0657．31 [文献标识码] A [文章编号] 1004—8685(2007)12—2225—03 Resin separation——determination of hexavalent chromium in products for drinking water and drinking water by AAS Shang Bo-dong，Zhang Wei，Lu lleng，Zhang Ming—yue (Tianjin Center for Disease Con~ol and Prevention，Tianjin 30001 1，China) [Abstract] Objective：To establish an graphite furnace atomic absorption spectrometry method for determination of hexavalent chromium in products for drinking water and drinking water．Methods：The pretreatment was performed using strong acid cation resin，with NH4 H2 PO4 as the anti—interference agenL GFAAS Was used to determination of hexavalent chromium in this study．Results：Using strong acid cation resin call effectively remove trivalent chromium and other ions coexist．With 10 g／L NH4H2PO4，precision and stability of determination can be improved，and also can reduce interference．The linear range of the de— termination Was 0～10．00 g／L Regression formula Was Y=0．0539X+0．006，r=0．9993．The detection limit of this method was 0．02 g／L，and the recovery Was at the range of 89％ ～108％． I1le RSD was 2．84％～7．14％．To contrast this method and the chemical GB，there Was no significant difference in the results．Condusion