油田采出水处理复合阻垢缓蚀剂的研究-表面技术.PDF

摇 摇 摇 表面技术 第43卷摇 第6期 ·116 · SURFACE TECHNOLOGY 摇 2014年12月 試試試試試試試試試試試試試試試試試試試試試試試試試試試試試試試試試試試試試試試試試試試試試試試試試 油田采出水处理复合阻垢缓蚀剂的研究 闫旭涛,刘志刚 (陕西省石油化工研究设计院 陕西省工业水处理工程技术研究中心,西安710054) 摘摇 要: 目的摇 制备一种高效、复合型的油田采出水处理阻垢缓蚀剂。方法摇 以二己烯三胺五亚甲基膦 酸、磺酸基共聚物和钨酸钠为原料复配成复合阻垢缓蚀剂,通过静态阻垢试验和动态腐蚀试验,研究复合 阻垢缓蚀剂的防垢和缓蚀效果与其质量浓度的关系,考察絮凝剂、杀菌剂及缓蚀剂等水处理剂对防垢效 果的影响。 结果摇 在油田采出水处理中,阻垢缓蚀剂最佳质量浓度为30 mg/ L,此时的阻垢率95%,腐 蚀速率为0.0696 mm/ a。 油田采出水中过量的絮凝剂及季铵盐1227 杀菌剂会造成阻垢率降低,咪唑啉 缓蚀剂对阻垢率有增效作用,异噻唑啉酮杀菌剂对阻垢率影响较小。 结论摇 该复合阻垢缓蚀剂生产制备 简单,阻垢和缓蚀性能优良。 关键词:阻垢缓蚀剂;阻垢率;油田采出水 中图分类号:TQ085摇 摇 摇 文献标识码:A摇 摇 摇 文章编号:1001鄄3660(2014)06鄄0116鄄05 Research of Composite Scale and Corrosion Inhibitor for Oilfield Produced Water Treatment YAN Xu鄄tao,LIUZhi鄄gang (Shaanxi Research Center of Industrial Water Treatment Engineering and Technology, Shaanxi Research Design Institute of Petroleum and Chemical Industry,Xi忆an710054,China) ABSTRACT:ObjectiveTodevelop anew typeof highly efficient composite scaleandcorrosioninhibitorfor oilfieldproducedwa鄄 ter treatment. MethodsAcompositescaleandcorrosioninhibitorwaspreparedusingbis(hexamethylenetriaminepenta(methylene phosphonic acid)),sulfonic acid copolymer and sodiumtungstate asraw materials. By the static scale inhibitiontest and dynamic corrosion test,the scale and corrosion inhibition performance were investigated at different mass concentrations of the composite scale and corrosion inhibitor. The influences of flocculant,corrosion inhibitors and bactericide on scale inhibition were studied. Results The scale inhibition ratewas over95% and the corrosion inhibition ratewas0.0696 mm/