稀土催化剂催化氧化甲苯研究 - 环境工程学报.doc

拟再审修改稿 稿件编号：201104055 LaxCe1-xMnO/γ-Al2O3催化剂的制备及催化氧化甲苯的研究 ，赵朝成 （中国石油大学，青岛 266555） LaxCe1-xMnO/γ-Al2O3稀土改性催化剂。考察了活性组分负载量、焙烧温度对催化剂影响确定催化剂的最佳制备工艺对影响LaxCe1-xMnO负载量%，催化剂的焙烧温度为0℃，LaCe物质的量比为 关键词 催化燃烧；稀土共掺；负载型催化剂；甲苯 中图分类号 X701.7 文献标识码 A Study on preparation of LaxCe1-xMnO/γ-Al2O3 catalysts for catalytic combustion of toluene Wang Shuai Zhao Chaocheng Wang Yongqiang (Department of Environmental Science and Engineering, China University of Petroleum, Qingdao 266555, China) Abstract In this paper, MnOx catalysts, supported on γ-Al2O3 and modified by La and Ce, were prepared by incipient wetness impregnation method. The loading amount of LaxCe1-xMnO, calcination temperature, and rare earth distribution ratio were investigated on toluene removal. It was found that the best preparation process of catalyst was that the loading amount of LaxCe1-xMnO was 12%, the calcination temperature was 450℃, and the ratio of La to Ce was 4:1. In the GHSV of 6000h-1, toluene was completely combusted at the temperature of 320℃. BET, XRD, SEM and XRF were employed in catalyst characterization. The results showed that the active component on the surface of La0.8Ce0.2MnO/γ-Al2O3 catalyst disperse evenly. The size of oxide particles on the surface of catalyst is equable. Compared to the single rare earth modified catalyst, rare earth co-doping catalyst is superior in loading on the supporters. Key word catalytic combustion; rare earth co-doping; supported catalysts; toluene 基金项目：(09CX04033A)资助 作者：（196-），，，主要从事研究。Email@ 挥发性有机化合物(VOCs)是一类主要的空气污染物，主要来自石油化工、油漆生产、金属涂装、印刷、包漆生产等不同行业[1-3]。这些易挥发性有机废气(VOCs)污染环境，危害人体健康[4]，必须进行净化处理。VOCs的处理技术主要是焚烧，焚烧处理的方式有直接燃烧和催化燃烧两种。催化燃烧技术相对于直接燃烧而言操作温度更低，而且不易产生二次污染，这些优点和节能的特性使之成为目前最有应用前景的VOCs处理方法之一。 目前，在催化燃烧催化剂的研究中，催化剂包括贵金属催化剂和非贵金属催化剂。贵金属催化剂如Pt、Pd、Rh[5-6]等，催化活性高且选择性好，但价格昂贵且稳定性差，易中毒，这些都限制了其普遍应用。过渡金属催化剂Cu、Co、Cr、Mn、Ni等，虽然活性不如贵金属催化剂高，但价格低廉，经助剂改性后制成复合氧化物催化剂，在一定的条件下可以达到贵金属催化剂的催化效果[7-8]。稀土元素是一种良好的助剂组分，我国盛产稀土。稀土元素具有较好的储氧功能，增进催化剂的热稳定性和机械强度[9-10]，因此一直是催化领域研究的热点。本文采用La、CeLa、