树形分子表面接枝.ppt

Surface Modification of Chitosan Powder by Grafting of dendrimer-like Hyperbranched Polyer onto the Surface;Introduction;Experimental;Grafting of dendritic PAMAM from chitosan powder surface by repeating two processes: (1)Michael addition of MA to amino groups on the surface (2)amidation of terminal ester groups by EDA. ;Preparation of living polymer cation of MeOZO and IBVE Postgrafting of living polymer cation to PAMAM grafted on chitosan powder Determination of percentage of grafting Determination of percentage of postgrafting and overall grafting Wettability of polymer-grafted chitosan powder surface Solubility of dendritic PAMAM- grafted chitosan ;Results and discussion; IR spectra of (A) untreated, (B) PAMAM dendrimer-grafted chitosan powder at fourth generation (grafting = 13.5%), and (C) at eighth generation (grafting = 180.6%);SEM aspects of dendritic PAMAM-grafted chitosan powder;Solubility of dendritic PAMAM- grafted chitosan powder;Postgrafting of dendritic polyamidoamine- grafted chitosan powder;;Wettability of dendritic PAMAM- grafted chitosan powder;Conclusions;3 PolyMeOZO and polyIBVE were readily postgrafted onto the hyperbranched dendritic PAMAM-grafted chitosan powder surface by the termination of the corresponding living polymer cation with terminal amino groups of the PAMAM-grafted chitosan powder. 4 Wettability of chitosan powder surface was controlled by the grafting of hyperbranched dendritic PAMAM and postgrafting of living polymer onto dendritic PAMAM-grafted chitosan powder.;Thanks!