第二章(同位素分馏)教程.ppt

The Atmospheric Reactor P Industry Volcanoes Marine Biogenics Biomass burning Continental Biogenics ? Deposition, Biosphere interaction Primary Species H2S, SO2, CH4, CO, CO2, NO, N2O, particulates Secondary Species CO2, H2SO4, HNO3, RCOOH Oxidation Capacity Photochemistry Radiative Budget Atmospheric Chemistry is controlled by atmospheric oxidants “The Earth’s oxidizing capacity” O3 CH4 CO HC NOx OH H2O2 hu, O(1D) O2, H2O O3, NO HO2 SOx H2SO4 SOx H2SO4 SOx H2SO4 NOx HNO3 NOx HNO3 大气化学被大气氧化剂控制 质量不相关分馏现象的发现及其对创新的启示 Bao, Huiming, Ian J. Fairchild, Peter M. Wynn, and Christoph Sptl, 2009, Stretching the Envelope of Past Surface Environments: Neoproterozoic Glacial Lakes from Svalbard, Science, 323, 119-122; DOI: 10.1126/science.1165373 Bao, Huiming, Jim Lyons, and Chuanming Zhou, May 2008, Triple oxygen isotope evidence for elevated CO2 levels after a Neoproterozoic glaciation, Nature, 453 (7194), 504-506; DOI: 10.1038/nature06959. Bao, Huiming, Sun, T., Kohl, I., and Peng, Y.-P., 2008, Comments on Early Archaean microorganisms preferred elemental sulfur, not sulfate, Science, v. 319 (5868), p. 1336. Bao, Huiming and Gu, Baohua, 2004, Natural perchlorate has a unique oxygen isotope signature. Environmental Science and Technology, 38(19): 5073-5077.; 10.1021/es049516z Bao, Huiming, Thiemens, M.H., Loope, D.B. and Yuan, X.-L., 2003. Sulfate oxygen-17 anomaly in an Oligocene ash bed in mid-North America: Was it the dry fogs? Geophysical Research Letters, 30(16): 1843; 10.1029/2003GL016869. Bao Huiming, Douglas A. Campbell, James G. Bockheim, Mark H. Thiemens, 2000, Origin of sulfate in Antarctic Dry Valley soils as deduced from anomalous 17O compositions. Nature 407, 499-502. Bao, Huiming et al. 2000, Anomalous 17O compositions in massive sulphate deposits on the Earth. Nature 406, 176-178. 麻黄素中δ2H、δ13C和δ15N的三维同位素组成图 Kurashima N, Makino Y, Urano Y, et al. Use of stable isotope ratios for profiling of industrial ephedrin