温度与活化源对活性碳纤维之微细结构与化学性质之影响.pdf

溫度與活化源對活性碳纖維之微細結構與化學性質之影響 The Study of the Effect of above the Temperature and Activator on the Chemical Properties and Microstructure of Activated Carbon Fabrics 曾梓倫、蘇清淵 Zih-Lun Zeng, Ching-Iuan Su 國立台灣科技大學 高分子工程研究所 Department of Polymer Engineering National Taiwan University of Science and Technology 曾梓倫 M9604101@mail.ntust.edu.tw 摘要 實驗中以嫘縈為前軀體，放入連續半開放式高溫爐經氧化 、碳化、活化工程一次完成， 製備ACF 。利用不同的碳化溫度和活化源來探討活性碳纖維布的微細結構與化學性質。並測 試ACF對有機氣體的吸附能力。由結果顯示，水蒸氣與空氣混合之活化源所製備之活性碳纖 2 維主要為微孔結構，BET比表面積最高達 1411.6 (m /g) ，而其結晶厚度較大為3.84 ，結構較緻 密，具有較高的真實密度值 2.59 (g/cm³) ，對四氯化碳氣體具有最大的吸附量97.5(%) 。 Abstract This experiment used viscose rayon-based as the Precursor, and placed it into continuous semi-open high-temperature erect furnace for oxidation, carbonization and activation, to prepare ACF. Different carbonization temperatures and activators were applied to discuss microstructure and chemical properties of activated carbon fabrics, and ACF capability of adsorbing organic gas was tested. The results showed that activated carbon fabric prepared by activator of blending vapor and air was primarily of microstructure, maximum specific surface area of BET reached 1411.6 (m2/g), and its crystallization thickness reached 3.84. Furthermore, the structure of such activated carbon fabric was relatively compact, with higher true