纳米级高岭土对氮、磷、钾和有机碳的吸附及解吸特性 - 中国农业科学.pdf

中国农业科学 2005,38(1):102-109 Scientia Agricultura Sinica 纳米级高岭土对氮、磷、钾和有机碳的吸附及解吸特性的研究 刘秀梅，张夫道，张树清，冯兆滨，何绪生，王玉军，王茹芳 （中国农业科学院土壤肥料研究所，北京 100081 ） 摘要：研究了纳米级和天然高岭土对营养元素氮、磷、钾和有机碳的吸附及解吸特性。结果表明，在相同 的初始处理浓度下，纳米级高岭土对氮、磷、钾和有机碳的吸附量均比天然高岭土高，氮的吸附量是天然高岭 土的 1.5~1.7 倍、磷是 1.9~2.2 倍、钾是 1.4~2 倍、碳是 1.3 ～1.9 倍。纳米级和天然高岭土对氮、磷、钾和有机 碳的解吸量与其吸附量呈正相关。2 种高岭土对氮、磷、钾和有机碳的吸附规律均可用Langmuir 和 Freundlich 方 程来拟合。 关键词：纳米级高岭土；吸附；解吸；方程 Study on Adsorption and Desorption Properties of Nano-kaoline to Nitrogen, Phosphorus, Potash and Organic Carbon LIU Xiu-mei, ZHANG Fu-dao, ZHANG Shu-qing, FENG Zhao-bin, HE Xu-sheng, WANG Yu-jun, WANG Ru-fang ( Soil and Fertilizer Institute, Chinese Academy of Agricultural Sciences, Beijing 100081 ) Abstract: This paper deals with the adsorption and desorption characteristics of kaoline to organic carbon and three nutrient elements, i.e. nitrogen, phosphorus and potash. The adsorption amounts of nano-kaoline to organic carbon , nitrogen, phosphorus and potash were higher than natural kaoline; especially, the adsorption amounts of nano-kaoline to nitrogen, phosphorus, patosh, and organic carbon were 1.5-1.7, 1.9-2.2 , 1.4-2.0, and 1.3-1.9 times higher than that of natural kaoline, respectively. The desorption amounts of natural kaoline and nano-kaoline increased with the increase of the adsorption amounts of organic carbon, nitrogen, phosphorus and potash. Both natural and nano-kaoline adsorption properties could be depicted with Langmuir and Freundlich equations. Key words: Nano-kaoline ; Adsorption ; Desorption ; Equation 中国高岭土资源丰富，矿床分布广泛，全国 16 缘性，将高岭土粉体加热至接近其熔点(一般超过 个省、自治区都有产出，但主要分布在东南沿海一带。 1 000℃)时，粉体物质自发地充填粒间隙，使高岭土 华东、中南地区探明储量为全国总储量的