掺杂锂镍钻锰氧材料的合成及电化学性能.pdfVIP

濠技 掺杂锂镍钴锰氧材料的合成及电化学性能 唐爱东，王海燕，吴 晓，黄可龙 (中南大学化学化工学院，湖南长沙410083) 摘要：采用改进的共沉淀法合成掺杂AI、Mg的LiNi C0 Mn 。O 系列材料，通过X射线衍射光谱法(XRD)、扫描电子 显微镜法(SEM)、伏安法(cv)、充放电测试、交流阻抗等技术对材料进行了表征，比较了掺杂元素(AI、Mg)对电化学性能 的影响。在2．8～4 3 V，0．1 C倍率下未掺杂材料的首次放电比容量达171．1 mAh／g，循环1O次后为1 52 2 mAh／g，掺 杂AI、Mg后容量有所下降，但循环性能得到改善，前1O次容量衰减分别为2．5％、3 3％。采用Voigt模型对交流阻抗谱 进行拟合，比较了电解液阻抗、交换膜阻抗和法拉第阻抗的变化，发现1O次循环后电荷传递阻抗明显增大 关键词：LiNi 3Co∞Mn 。O2；正极材料；掺杂；电化学性能 中图分类号：TM 912．9 文献标识码：A 文章编号：1002—087 X(2007)12—0959—04 Synthesis and electrochemical properties of doped Li．．Ni．．Co．．Mn．．O materials TANG Ai—dong，WANG Hai—yan．WU Xiao．HUANG Ke—long (College ofChemistry andChemicalEngineering,CentralSouUniversity,ChangshaHunan 410083，China) Abstract： The layered LiNi1。Co∞Mn1 3O2 cathode materials doped with AI and Mg were synthesized by c0一precipitated， and the materials were characterized by XRD． SEM， CV． charge—discharge test． and AC impedance．The effects of different doped elements (AI，Mg)on electrochemical properties of the synthesized materials were also studied．The first discharge capacity of un—doped material was 1 71 1 mAh／g．and 1 52．2 mAh／g was reached after 1 0 cycles at 2，8—4．3 V 0．1 C rate The cycling properties of the doped element(AI Mg)materials were improved．Their capacity fade rates were only 2．5％ and 3．3％ after 10 cycles．respectively．Compared with the change of solution impedance， double layer capacitance and charge transfer impedance by AC impedance Voigt mode1 were made．it was clear that charge transfer}mpedance increased obviously after 1 0 cycles． Key words：LiNii Coi3Mni 3O2：cathode material；doped；electrochemical property 目前，锂离子电池正橄材料主要有锂钻氧、锂镍氧和锂锰 与一定浓度的NaOH溶液分别同时缓慢