生物油中酚类化合物加氢脱氧催化剂研究进展 - 催化学报.pdfVIP

2012 Chinese Journal of Catalysis Vol. 33 No. 2 文章编号: 0253-9837(2012)02-0215-07 DOI : 10.3724/SP.J.1088.2012.10922 综述: 215~221 生物油中酚类化合物加氢脱氧催化剂研究进展 * 王威燕, 张小哲, 杨运泉 , 杨彦松, 彭会左, 刘文英 湘潭大学化工学院, 湖南湘潭 411105 摘要: 随着化石能源日益匮乏, 生物质热裂解制备生物油广受关注. 然而, 生物油中含有大量酚、呋喃、醛、酮等含氧化合物, 含 氧量高达 50%, 导致其热值低、化学稳定性差等, 因而阻碍了它的广泛应用, 必须对其进行加氢脱氧精制降低含氧量. 在生物油 中众多含氧化合物中, 酚羟基氧被认为是最难被脱除的. 对酚类含氧化合物加氢脱氧催化剂及反应进行了简单综述, 并提出了 如何进一步提高催化剂性能的有效方法. 关键词: 酚类化合物; 加氢脱氧; 生物油; 清洁燃油 中图分类号: O643/X7 文献标识码: A 收稿日期: 2011-09-22. 接受日期: 2011-10-31. *通讯联系人. 电话: (0731 传真: (0731 电子信箱: yangyunquan@ 基金来源: 湖南省教育厅开放基金 (10K062); 教育部化工过程模拟与优化工程研究中心开放基金 (2008HGZX02). Progress in the Catalysts for the Hydrodeoxygenation of Phenols in Bio-oil * WANG Weiyan, ZHANG Xiaozhe, YANG Yunquan , YANG Yansong, PENG Huizuo, LIU Wenying School of Chemical Engineering, Xiangtan University, Xiangtan 411105, Hunan, China Abstract: With the declining of crude oil resources, the development of bio-oil from biomass into fast pyrolysis has attracted much attention. However, the bio-oil contains many oxygenic compounds such as phenols, funans, aldehyde, ketone, etc., and its oxygen content is high up to 50%, leading to its low heating value and thermal instability, which hinders its extensive application. It is necessary to remove the oxygen from bio-oil by a hydrodeoxygenation (HDO) process. Among many oxygenic compounds, phenolic hydroxyl oxygen is considered the most difficult one to be removed. The HDO of phenols was reviewed and the effectiv