硫化锌–氧化锌之奈米核–壳结构的制备及特性研究 - 国立交通大学 .pdfVIP

硫奈 立料 奈料 力奈料 奈料領 論 奈論 兩利硫 硫 論 硫奈 利度 200 C 六 wurtzite 硫奈奈 100 nm 度 數 nm 利 度 500 2000 nm 20 150 nm 硫奈ZnS 0.5en 硫奈行 650 C 3 理 奈 X-ray 硫 i 見 490 500 nm 藍綠 論 利 奈列 理降 量 奈奈列 度 奈列硫 行硫硫奈XPS 硫奈硫 量 奈6 兩硫奈 料來 ii Preparation and Characteristic of ZnS-ZnO Core-Shell Structure Student Pai-Chia Kuo Advisor Dr. San-Yuan Chen Department of Materials Science and Engineering National Chiao Tung University Abstract Nanomaterials have extraordinary functionality and strong potential for future development. Preparation methodology of nanomaterials have since been an important research field. In this work our emphasis lays on the preparation of one dimensional core-shell structure. We use two different ways to fabricate ZnS-ZnO core-shell structure, namely hydrothermal method and atomic layer deposition method. Wurtzite ZnS nanorods are obtained through hydrothermal processing for 6 hours under 200 using ethylenediamine of specific concentration as solvent. The diameter of the nanorods is smaller than 100 nm and the length of them is around several hundred of nanometers. Moreover, ZnS nanorods are also synthesized by codeposition under room temperature using ethylenediamine as solvent. These rods have a length from 500 to 2000 nm and a diameter from 20 to 150 nm. However, ZnS nanorods synthesized in this way contain un-decomposed ZnS 0.5en. Surfaces of the rods are oxidized by heating under 650 for 3 mins in iii an oxygen atmosphere. ZnS-ZnO core-shell structure is examined by XRD and SEM. The luminescence of core-shell structure is mainly in the visible region, with its PL