印刷线路板含铜废蚀刻液的回用处理(二).pdfVIP

印刷线路板含铜废蚀刻液的回用处理(二) 胡耀红*，赵国鹏，谢素玲，袁国伟，张招贤 （广州市二轻工业科学技术研究所，广东广州 510663 ） 摘 要：介绍了几种印刷线路板铜蚀刻废液的回用处理工艺(如 电解再生法、氧化再生法)及其所用材料(包括电极和萃取剂)， 概述了几种从铜蚀刻废液中回收资源的方法(如利用碱氨蚀刻 废液制备胆矾或氯化亚铜)。 关键词：印刷线路板；铜蚀刻液；处理；回用；再生 中图分类号：X781.1; TN41 文献标志码：A 图 1 连续式酸性蚀铜再生系统 文章编号：1004 – 227X (2009) 11 – 0036 – 05 Figure 1 System for continuous regeneration of acid Reuse treatment of spent copper-containing etching copper-etching solution solution for printed circuit board—Part II // HU 及配备了不锈钢(SS)的阴极区。阴阳二极有效面积均 Yao-hong*, ZHAO Guo-peng, XIE Su-ling, YUAN 2 为 4 300 cm 。控制流量，经过一定的反应时间后，再 Guo-wei, ZHANG Zhao-xian Abstract: Several treatment processes (such as electrolytic 生液由电化学反应槽回流至蚀铜槽。此再生实验恒电压 regeneration and oxidative regeneration methods) for reuse 6.0 V，恒电流20 A ，相应的电流密度为2.33 mA/cm2 。 of spent copper-etching solution from the production of 4. 1. 1 ORP 值与一价铜离子质量浓度的关系 printed circuit board and the materials used (including 再生反应进行时，只需测定 ORP 值就可以知道溶 electrodes and extracting agents) were introduced. Some 液中一价铜离子的质量浓度，两者的关系如图 2 所示。 methods for recovering recourses from spent copper-etching solution, such as using spent alkaline ammonia etching solution to prepare blue vitriol or copper(I) chloride, were described. Keywords: printed circuit board; copper-etching solution; treatment; reuse; regeneration Author’s address: Guangzhou Etsing Plating Research Institute, Guangzhou 510663, China