添加剂Pr2O3 和Er2O3 对电沉积Ni-S 合金电极 - 中国有色金属学报.PDF

文章编号：1004-0609(2008)05-0862-05 添加剂Pr O 和Er O 对电沉积Ni-S 合金电极性能的影响 2 3 2 3 袁铁锤，周科朝，李瑞迪 ( 中南大学 粉末冶金国家重点实验室，长沙 410083) 摘 要：以氧化镨、氧化铒为添加剂，在泡沫镍基体上电沉积制备 Ni-S 镀层电极。对镀层的表面形貌、镀层结 构、电沉积行为及镀层的电化学性能进行研究。结果表明：电镀液中添加稀土氧化物后电沉积过程的阴极极化增 强，沉积层晶粒细化，比表面积增大，因而电极的析氢过电位降低；其中，添加 Pr2O3 的Ni-S 镀层在 250 mA/cm2 下碱性水电解时过电位降低达 37 mV，且该镀层电极在碱性介质下具有较高的析氢活性和耐腐蚀性能，在 100 h 水电解实验中表现出较强的稳定性。 关键词：氧化镨；氧化铒；Ni-S 合金；电沉积；析氢反应 中图分类号：TQ 153.2 文献标识码：A Effect of additives Pr O and Er O on properties of 2 3 2 3 electrodeposited nickel sulphur alloy electrode YUAN Tie-chui, ZHOU Ke-chao, LI Rui-di (State Key Laboratory of Powder Metallurgy, Central South University, Changsha 410083, China) Abstract: Ni-S coating electrodes were prepared on the foam nickel substrates by electrodeposition method with Pr O or 2 3 Er2O3 as additives. The effects of the rare earth compounds on the grain sizes, textures, microstructures and electrochemical activities of Ni-S coatings were studied. The results show that the rare earth oxides added in electrolyte can increase the cathode polarization. The Ni-S coatings with additives have larger surface area and smaller grain sizes. The hydrogen evolution overpotential of Ni-S(Pr O ) alloy coatings decreases, it exhibits higher hydrogen evolution 2 3 activities and better corrosion resistant performance in alkaline water. The hydrogen evolution overpotential of