油藏矿物和化学剂强化稠油水热裂解降黏研究.pdfVIP

第36卷 第3期 燃 料 化 学 学 报 VO1．36 NO．3 2008年6月 Journal of Fuel Chemistry and Technology Jun．2oo8 文章编号：0253-2409(2008)03-0302-04 油藏矿物和化学剂强化稠油水热裂解降黏研究 刘永建，胡绍彬，闻守斌，赵法军 (大庆石油学院提高油气采收率教育部重点实验室，黑龙江大庆 163318) 摘 要：采用大庆、辽河两种稠油，研究了油藏矿物、硫酸镍催化剂以及四氢萘供氢剂对其水热裂解反应的影响。结果表明， 与单纯水热裂解相比，油藏矿物的加入能使两种稠油的平均相对分子质量减小，饱和烃和芳香烃组分含量增加，胶质和沥青 质组分含量减少，稠油的降黏率分别从7．41％和12．95％增加到16、05％和25．29％，油藏矿物对稠油水热裂解反应具有催化 作用；将硫酸镍和四氢萘加入反应体系后，稠油平均相对分子质量进一步降低，族组分中饱和烃和芳香烃进一步增加，胶质和 沥青质组分进一步减少，稠油黏度明显降低，降黏率可高达84．39％。 关键词：稠油；水热裂解；油藏矿物；催化；降黏 中图分类号：TE345 文献标识码：A Enhance viscosity reduction of heavy oil by using reservoir minerals and chemical agents in aquathermolysis LIU Yong-jian，HU Shao—bin，WEN Shou—bin，ZHAO Fa—jun (Enhanced Oil Recovery Key Laboratory，Ministry ofEducation，Daqing Petroleum Institute，Daqing 163318，China) Abstract：Through laboratory experiments with samples from Daqing and Liaohe oilfields，the effects of reservoir mineral，NiSOd and tetrahydronaphthalene(THN)on the aquathermolysis(AT)of heavy oil were investigated．The results indicate that，in contrast with simple AT．the addition of reservoir minerals leads to lower average molecular weight，higher contents of saturated and aromatic hydrocarbon fractions and lower contents of resin and asphaltene fractions，and the viscosity reduction ratio of the two oil samples increases from 7．41％ and 12．95％ to 16．05％ and 25．29％ respectively．which means that reservoir minerals can catalyze the AT of heavy oil．With the addition of NiS0d and THN into the reaction system，the average molecular weight of the reaction products decreases further，the contents of saturated and aromatic hydrocarbon fractions increase and the contents of resin and asphaltene fractions decrease further，the viscosity decreases greatly with a reduction ratio as high as 84．39％ ． Key word