磷酸催化竹材炭化的FT- IR分析 - 林产化学与工业.PDF

25 4 Vo.l 25 No. 4 2005 12 Chem istry and Industry of Forest Products Dec. 2005 FT- IR 1, 2 1 左宋林 , 江小华 ( 1. 南京林业大学 化学工程学院, 江苏 南京 210037; 2. 南京大学 介观化学教育部重点实验室, 江苏 南京 210039) : 通过比较分 不添加和添加磷酸的竹材在不同炭化温度的炭化固体产物的红外光 谱, 探讨了磷酸对竹材热解过程以及所形成的炭的微观结构变化的催化作用结果显示: 1)磷 ZUO S L 酸能显著地催化竹材的主要成分(尤其是木质素) 的热分解; 同时能显著地催化芳环的形成和 稠合, 从而促进类石墨微晶的形成; 2)在磷酸的催化下, 400 前是竹材中主要化学成分的热分解和芳环的形 成过程, 而 400 后是芳环的形成芳环的稠合以及类石墨微晶的形成过程; 3) 红外光谱是研究炭化植物纤 维中半纤维素纤维素和木质素的热解变化过程和炭化产物炭微观结构的形成和发展的有效手段 : 竹材; 磷酸; 热解; 炭化 : TQ351. 2 : A : 0253- 24 17( 2005) 04- 0021- 05 FT-IR ANALYSIS OF CARBON IZED BAMBOO CATALYZED BY PHOSPHOR IC ACID 1, 2 1 ZUO Song-lin , JIANG X iao-hua ( 1. Colleg e of Chem ica lEngineering, N anj ing Forestry Univers ity, Nanj ing 210037, China; 2. M esoscop y Chem istry of K ey Laboratory of E uca tionM in istry, N anj ing University, Nanj ing 210039, China) A bstrac t: Fourier transform infrared ( FT-IR) spectroscopy was used in attem pt to illustrate the pyrolysis of bamboo and evolution of chars under the catalysis of phosphoric acid. FT-IR spectra indicate that phosphoric acid can sign if-i cantly catalyze the pyrolysis of the chem ical components, especially the pyrolys is of lign in, form ation and condensa- tion of arom atic rings, and form ation of graphite-like m icro-crystals in chars. In the case of phosphoric acid as catalyst, the course of bamboo carbon ization can be d ivided into wt