非均匀分布Pd／Al2O3催化剂活性组分Pd的迁移及其对加氢性能的影响.pdfVIP

石油学报(石油加工) 2008年4月 ACTA PETROLEI SINICA(PETROLEUM PROCESSING SECTION) 第 24卷第 2期 文章编号：1001—8719(2008)02—0158—05 非均匀分布 Pd／Al2 o3催化剂活性组分Pd 的迁移及其对加氢性能的影响 赵振兴 ，夏春谷 ，薛群基 (1．中国科学院兰州化学物理研究所，甘肃 兰州 730000；2．中国科学院研究生院，北京100049) 摘要：研究了具有壳层结构的负载型Pd／Al 0。催化剂在裂解汽油选择性加氢过程中活性组分 Pd的迁移现象。测 定了生产装置所用新鲜催化剂和再生催化剂的比表面积、孔容和其中活性组分 Pd含量，采用 TEM和 SEM—EDS 方法表征了Pd的分散性。结果表明，在裂解汽油选择性加氢的工艺过程中，具有壳层结构的负载型 Pd／Al 0 催 化剂的永久性失活和选择性改变的主要原因之一是活性组分 Pd的迁移。Pd迁移的基本原因是其在催化剂颗粒中 的不均匀分布，助金属组分可以限制 Pd的迁移，从而改善催化剂的性能。 关 键 词：负载型 Pd／A1zO 催化剂；壳层结构；裂解汽油；选择性加氢；活性组分；迁移 中图分类号：TE624．9 文献标识码：A MIGRATIoN oF THE ACTIVE Pd IN Pd／AI2 O3 CATALYST WITH A NoNUNIFoRM DISTRIBUTIoN AND ITS EFFECT oN SELECTIVE HYDRoGENATIoN ZHAO Zhen—xing ，XIA Chun—gu ，XUE Qun—ji (1．Lanzhou Institute of Chemical and Physics，The Chinese Academy of Sciences，Lanzhou 730000，China 2．Graduate School of the Chinese Academy of Sciences，Beijing 100049，China) Abstract：The migration of active Pd in the supported Pd／A12 O3 catalyst with the eggshell profile during the process of pyrolysis gasoline partial hydrogenation was investigated．The Pd content， BET surface area，pore volume of both the fresh and the regenerated catalysts sampled from the commercial plant were determined．The dispersion of Pd／A12 O3 was characterized by TEM and SEM—EDS methods．The results indicated that one of the major factors affecting the catalyst deactivation abidingly and changing the catalyst selectivity for the selective hydrogenation of pyrolysis gasoline was the migration of active Pd． The basic reason of Pd migration is the nonuniform distribution of Pd in Pd／A12 O3 catalyst，and the addition of some metal in Pd／A12 O3 can restrain the Pd migration to improve the performan