钛酸钡纳米颗粒聚集球的形成机理 - ingenta connect.pdf

See discussions, stats, and author profiles for this publication at: /publication/263072220 Formation Mechanism of Barium Titanate Nanoparticle Aggregations Article in AC A PHYSICO-CHIMICA SINICA · December 2011 DOI: 10.3866/PKU.WHX CI A IONS READS 3 20 6 authors, including: Yue-Ming Li Jingdezhen Ceramic Institute 109 PUBLICA IONS 910 CI A IONS SEE PROFILE Some of the authors of this publication are also working on these related projects: Condensate Project View project bio-sepration View project All content following this page was uploaded by Yue-Ming Li on 11 February 2016. he user has requested enhancement of the downloaded file. All in-text references underlined in blue are added to the original document and are linked to publications on ResearchGate, letting you access and read them immediately. 物理化学学报(Wuli Huaxue Xuebao) December Acta Phys. -Chim. Sin. 2011, 27 (12), 2927-2932 2927 [Article] doi: 10.3866/PKU.WHX 钛酸钡纳米颗粒聚集球的形成机理 展红全 江向平* 李小红 罗志云 陈 超 李月明 (景德镇陶瓷学院材料科学与工程学院, 江西省先进陶瓷材料重点实验室, 江西景德镇333403) 摘要: 采用水热法合成了具有新颖结构的钛酸钡纳米颗粒聚集球. X 射线衍射(XRD)结果显示该聚集球为立 方相, 随着时间的延长其结晶性增强. 利用扫描电子显微镜(SEM)、透射电子显微镜(TEM)、高分辨透射电子显 微镜(HRTEM)和电子衍射(ED)谱研究了该纳米颗粒聚集球的生长特点. 结果表明该聚集球是由5-8 nm 的纳 米颗粒定向连接生长而成, 整个聚集球对外显示类单晶的现象. 聚集球的大小约为60 nm, 随着时间的延长有 长大的趋势. X 射线能谱(EDX)分析结果和Johnson-Mehl-Avrami (JMA)方程动力学模拟结果表明, 在颗粒球 形成初始阶段主要是Ba2+离子的扩散成核作用占主导地位. 这种“扩散成核-定向生长”的形成过程揭示了钛酸 钡纳米颗粒聚集球的生长机理. 关键词: 钛酸钡; JMA 方程; 水热法; 扩散机理; 定向生