阳离子絮凝剂木质素季胺盐的合成与脱色性能研究 - 林产化学与工业.pdf

23 2 Vol. 23 No. 2 2003 6 Chemistry and Industry of Forest Products June 2003 1 1 2 方桂珍 , 何伟华 , 宋湛谦 ( 1. 东北林业大学 材料科学与工程学院, 黑龙江 哈尔滨 150040; 2. 中国林业科学研究院林产化学工业研究所, 江苏 南京 210042) FANG G Z : , , , ( FTIR) , ATT , , : - 3 - 6 , 10.7, , , 0. 5% , (pH 2~ 3) , 2~ 3 g/ L : ; ; :TQ351. 377 :A :0253- 2417(2003) 02- 0037- 05 YNTHE I AND PERFORMANCE OF QUATERNARY AMMONIUM ALT OF LIGNIN A CATIONIC FLOCCULANT 1 1 2 FANG Gu-i zhen , HE We-i hua , ONG Zhan-qian (1. College of Material Science and Engineering,Northeast Forestry University, Harbin 150040, China; 2.Institute of Che ical Industry of Forest Products, CAF,Nanj ing 210042, China) Abstract: Cationic flocculant of quaternary ammonium salt of lignin was synthesized using sulphate lignin from papermaking black liquor .The decolourizing performance of quaternary ammonium salt of lignin and effects of different catalysts on the synthesiswere studied. Quaternary ammonium salt of lignin was investigated through infrared spectrum( FTIR) . Flocculation performance of the salt applied to dye liquor of high concentration and high colority has been quantitatively analysed. Results indicate that cationic flocculant of quaternary ammonium salt of lignin can be synthesized by grafting reaction. ynthesis of monomeric quaternary ammonium salt was carried out at: mole ratio of tr-i methylamine and chloro-cyclopropane 10. 7, tem- perature from - 3 to - 6 .Ammonium