机械研磨时间对铜基甲醇合成催化剂性能的影响 - 化学通报.pdf

化学通报 2012 年 第 75 卷 w2012003 研究简报 机械研磨时间对铜基甲醇合成催化剂性能的影响 苏国栋 林笑笑 雷 宏* (衢州学院化学与材料工程学院 浙江衢州 324000) 摘 要 采用机械研磨燃烧法在不同研磨时间下制备了系列 Cu/ZnO/Al O 催化剂，并评价了其在一氧化 2 3 碳加氢制备甲醇反应中的活性。催化剂前驱体的焙烧过程通过热重-差热分析仪(TG-DSC)监测。采用 X 射线衍 射(XRD)、扫描电镜(SEM)、N 吸附、程序升温还原(TPR)和 N O 氧化后氢气滴定等方法对催化剂进行了表征。 2 2 结果表明，催化剂的结构性质与研磨时间密切相关，催化剂的比表面积和铜原子的分散度随研磨时间延长先增 大后减小，研磨 2 h 制得的催化剂显示了最高的催化活性。 关键词 机械研磨燃烧法 Cu/ZnO/Al2O3 催化剂 研磨时间 一氧化碳加氢 甲醇 Influence of Mechanical Grinding Time on Properties of Cu-based Catalyst for Methanol Synthesis Su Guodong, Lin Xiaoxiao, Lei Hong* (College of Chemical and Material Engineering, Quzhou University, Quzhou 324000) Abstract Cu/ZnO/Al O catalysts were prepared using mechanical grinding and combustion method and tested 2 3 for the synthesis of methanol from CO hydrogenation. The calcination processes were monitored with TG-DSC. The catalysts were characterized by XRD, SEM, N adsorption, TPR and N O oxidation and followed H titration. The 2 2 2 results showed that the physicochemical properties of the as-prepared catalysts depend strongly on grinding time, and the BET surface area and the dispersion of copper species exhibit a volcano variation trend with an increase in grinding time. The catalyst obtained by grinding for 2 h exhibits the highest activity. Keywords Mechanical grinding and