第二章 气体分子运动论的基本概念（Chapter two basic concepts of kinetic theory of gases）.docVIP

第二章 气体分子运动论的基本概念（Chapter two basic concepts of kinetic theory of gases） Chapter two basic concepts of kinetic theory of gases Limiting vacuum of currently available for 2-1 in the order of 10 to 13 MMHG, ask how much per cubic centimeter under the vacuum air molecules, the air temperature is 27 ℃. Solution: P = n K T N = P = = 3.21 x 109 / KT (m - 3) Note: 1 MMHG = 1.33 x 102 n/m2 The wavelength of 2-2 sodium yellow light is 5893, or 5.893 x 10-7m. Imagine a cube length of 5.893 x 10-7m, and ask how many air molecules there are in standard condition. Solution: ∵ P = nKT ∴ PV = nKT Where T = 273K P = 1.013x105n/m2 ∴ N = a A vacuum system with a capacity of 11.2 L has been pumped to a 1.0 x 10-5mmhg vacuum. In order to improve the vacuum degree, put it in 300 ℃ baking in the oven, make the wall release gas adsorption. If the pressure is increased to 1.0x 10-2mmhg after baking, how many molecules of gas have been absorbed in the wall of the wall. Solution: the number of molecules in the container before baking is N. The number of molecules after baking is N. According to the formula, PV = NKT is: Since P0 is 103 compared with P1, the temperature difference before and after baking can be ignored compared with the pressure difference, so it can be neglected compared with that a The 2-4 volume is 2500cm3 with a 1.0 x 1015 oxygen molecule, a 4.0 x 1015 nitrogen molecule and 3.3 x 10-7g argon gas. Set the temperature of the mixed gas to 150 ℃, and the pressure of the mix. Solution: according to the pressure formula of the mixture PV = (N oxygen + N + N argon) KT The number of molecules in argon: N argon = (1) ∴ P = (1.0 + 4.0 + 4.0) 1015 pa mmHg 2-5 container is oxygen, P = 1.0 ATM its pressure, and temperature for t = 27 ℃, please (1) the number of molecules in the unit volume: (2) the density of oxygen; (3) the quality of the oxygen molecules; (4) the mean distance between molecules; (5) average translational energy of the molecule. Solution: (1) the ∵ P = nKT ∴ n = m -