第二章 单级平衡过程（Chapter ii process of single-stage equilibrium）.docVIP

第二章 单级平衡过程（Chapter ii process of single-stage equilibrium） Chapter ii process of single-stage equilibrium Chapter2 Single stage balance process Single-stage equilibrium separation refers to the process of separation after a close contact between the two phases, which can play a balancing role due to the difference of the composition of the two phases. The phase equilibrium is used to illustrate the separation principle, mass transfer and design calculation of the mixture. Vapor liquid equilibrium § 2-1 (Vapour - liquid phase equilibrium) A phase equilibrium is when two or more phases are in equilibrium. Balance means that the trend of changing the nature of the system over time has reached zero. The term phase means that any quantity of matter is uniformly and uniformly in the space occupied by it, and there is no discontinuity. A certain amount of matter, even if it is divided into parts, can be called an homogeneous as long as they are identical in nature and composition. If there are two or more than two homogeneous, although they close contact with each other, but their respective property does not change with time and, usually, can use balanced this word to express a state. For the equilibrium relationship between the temperature and pressure of the two-component system, it is often used to measure the equilibrium relationship between the two components, and the phase equilibrium relationship of the multi-component system is complicated by the experimental method. With the deepening of the phase equilibrium theory, the two components and vapor liquid equilibrium of multicomponent system has established some quantitative relation, using the relation, it only need to use a small amount of bicomponent of experimental data, which will greatly reduce the workload of the experiment. I. vapor-liquid phase equilibrium 1. Basic relations Phase equilibrium condition: the chemical level of component I in the vapor liquid phase is equal, It can also be expressed as compone