香附及其伪品天葵子的衰减全反射傅里叶变换红外光谱鉴别 - 中国药房.pdf

香附及其伪品天葵子的衰减全反射傅里叶变换红外光谱鉴别及 聚类分析 1＊ 2 2 胡 晔 ，万茶艳 ，程存归 （1.金华市中心医院药剂科，浙江金华 321000；2.浙江师范大学化学与生命科学学 院，浙江金华 321004） 中图分类号 R927 文献标志码 A 文章编号 1001-0408（2014）43-4103-03 DOI 10.6039/j.issn.1001-0408.2014.43.25 摘 要 目的：建立快速鉴别香附及其伪品天葵子的方法。方法：采用衰减全反射傅里叶变换红外光谱（ATR-FTIR ）技术获得香 附及天葵子的红外光谱，对其进行分析，并用聚类分析法对不同炮制方法（烘、蒸、煮）所得到的香附及天葵子进行进一步分析。结 果：香附及天葵子的红外光谱吸收峰位、峰强有较大的区别。聚类分析结果表明，同一种中药材经不同方法炮制后的结构信息基 本一致，所含化学成分具有一定的相似性。结论：该方法快速、简单、特征性强，可用于对香附及天葵子进行快速鉴别。 关键词 香附；天葵子；衰减全反射傅里叶变换红外光谱；鉴别 Identification of Cyperus rotundus and Counterfeit Product Semiaquilegia adoxoides Using ATR-FTIR and Their Cluster Analysis 1 2 2 HU Ye ，WAN Cha-yan ，CHENG Cun-gui （1.Dept. of Pharmacy ，Jinhua Municipal Central Hospital ，Zhejiang Jinhua 321000，China ；2.College of Chemistry and Life Science ，Zhejiang Normal University ，Zhejiang Jinhua 321004，China ） ABSTRACT OBJECTIVE ：To establish the method for rapid identification of Cyperus rotundus and counterfeit product Semiaguilegia adoxoides. METHODS ：The IR spectrum of C. rotundus and S. adoxoides were obtained by ATR-FTIR ；C. rotundus and counterfeit product S. adoxoides prepared by different processing methods （baked ，steamed ，boiled ）were further analyzed by cluster analysis. RESULTS ：There were large differences from the infrared absorption peak position and intensity of C. rotundus and S. adoxoides. The results of cluster analysis showed that same kind of Chinese medicinal materials processed by different methods showed same structure and similar chemical structure. CONCLUSIONS ：The method is rapid ，simple and characteristic ，and can identify C. rotundus and S. adoxoides rapidly. KEYWORDS Cyperus rotundus ；Semiaguilegia adoxoides ；ATR-FTIR ；Identification 香附（Cyperus rotundus ），别名香头草、莎草根等，始载于 香附为莎草科植物莎草C. rotundus L. 的干燥根茎；天葵 《名医别录》，列为中品。其味辛、微苦，性甘、平，具有疏肝解 子为毛茛