撒基铁催化黄槽油素、丁香盼异构化反应的研究studies on .pdf

第 8 期 1984 年 12 月 有机化学 陆6. Dec. , 1984 撒基铁催化黄槽油素、丁香盼异构化反应的研究 1 .反应机理的研究 卢兴梁胡建国 宁苟栓 (复旦大学化学系〉 摘.1 本文进一步研究了默基铁络合物光催化黄棒油素(1)和丁香盼(2)异构化反应的机理。 催化剂 Fe(CO)4(butadiene) 和 Fe(CO)3(butadi凹的对1 和 2 具有几乎相同的活化能以及动力学参 数 (m，时，这说明反应可能经过同一类型的过i度态。 j 在 320~610 nm 间进行光异构化反应时，只要光的波长能分解催化剂，则反应就能进行，这说明 1 反应的关键是配位不饱和鼓基铁与烯炬络合物的生成。， 叙调z 香精油，棋基络合物，异构化反应，反应机理，铁络合物。 I Studies on Isomerization of Safrole and Eugenol with Iron Carbonyls 111. Mechanism Lu Xingliang Hu Jianguo Ning Goushuan (Department 01 Chemistry, Fudan University, Shanghai) Abstract: This paper reports the mechanism of photoisomerization of safrole (1) and eugenol (2) with pentacarbonyl iron. The coordinatively unsaturated iron carbonyls are shown to be the catalysts. since Fe(CO)4(butadiene) and Fe(CO)3(butadiene) have a good catalytical ability. The active energy and other kinetic parameters from different catalysts. Fe(CO). (butadiene) and Fe(CO)3(butadiene). are approximately equa l. This can be rationalized by assuming that there is probably the same transition state on the isomeri7.ation. In the photoisomerization using seven monochromatic lights between 320-610 nm. the wave- length of light source is only connected with energy needed by dissociated catalyst. The key of the reaction is to produce the complexes of unsaturated coordinatively iron car- bonyls and alkenes. Descriptor I essential oiL carbonyl complex. isomerization. reaction mechanism. iron complex. 前文川