phase and chemical transformations in the sio2–fe2o3(fe3o4 .pdf

ISSN 0036-0236, Russian Journal of Inorganic Chemistry, 2006, Vol. 51, No. 1, pp. 118–125. © Pleiades Publishing, Inc., 2006. Original Russian Text © L.P. Mezentseva, V.F. Popova, V.I. Al’myashev, N.A. Lomanova, V.L. Ugolkov, S.V. Beshta, V.B. Khabenskii, V.V. Gusarov, 2006, published in Zhurnal Neorganicheskoi Khimii, 2006, Vol. 51, No. 1, pp. 126–133. PHYSICOCHEMICAL ANALYSIS OF INORGANIC SYSTEMS Phase and Chemical Transformations in the SiO –Fe O (Fe O ) System 2 2 3 3 4 at Various Oxygen Partial Pressures L. P. Mezentseva*, V. F. Popova*, V. I. Al’myashev*, N. A. Lomanova*, V. L. Ugolkov*, S. V. Beshta**, V. B. Khabenskii**, and V. V. Gusarov* * Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, ul. Odoevskogo 24/2, St. Petersburg, 199155 Russia ** Aleksandrov Research Technological Institute, Sosnovyi bor, Leningrad oblast, Russia Received February 8, 2005 Abstract—The SiO –Fe O (F O ) system has been studied in air, oxygen, and an inert atmosphere. The dis- 2 2 3 3 4 sociation temperatures for iron oxides, the onset and full melting temperatures for coexisting phases, and the melt demixing temperatures have been determined as a function of the oxygen partial pressure. A scenario of the phase and chemical transformations in the title systems has been developed. DOI: 10.1134/S0036023606010190 Oxide systems containing iron and silicon are of sig- Extrapolating the data on the SiO –FeO