无机化学第四版下册16章习题答案（The fourth edition of inorganic chemistry is under chapter 16）.doc

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无机化学第四版下册16章习题答案（The fourth edition of inorganic chemistry is under chapter 16）.doc

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无机化学第四版下册16章习题答案（The fourth edition of inorganic chemistry is under chapter 16）

无机化学第四版下册16章习题答案（The fourth edition of inorganic chemistry is under chapter 16） Chapter 16 nitrogen and phosphorus arsenic 16-1 please answer the following questions about the nature of nitrogen: (1) why does the n-n bond have a smaller bond energy (167kJ. Mol - 1) than the p-p key (201 kJ. Mol -1)? And then the bond of N is congruent with N bonds, which is 942 kilojoules per mole, which is bigger than P, which is the same thing as P, which is 481 kilojoules. (2) why cant nitrogen form five halides? (3) why is the first ionization energy of N2 less than the N atom? 1. Solution: (1) N, because of the small inner layer electron, the atomic radius is small, and the valence electron layer has no d orbital that can be used for bonding. The n-n single key can be anomalously smaller than the P - P bond in the third period, and N is easy to form the p-p key (including the delocalized key), so N = N and NN multiple keys can be larger than other elements. (2) the valence electron layer has no d orbital that can be used for bonding, and N can only form up to 4 covalent bonds, which means that N has no more than 4. (3) the p orbital of the valence shell electron is in a semi-full state. 16-2 please answer the following questions: (1) how do I get out of N2 with a small amount of NH3 and NH3? (2) how to remove a small amount of NO in NO2 and N2O in NO? 2. Solution: (1) to pass gas through dilute H C solution; Alkali lime (2) through NaOH solution; The strength of the bond between H2O, NH3 and proton is discussed. Why is acetic acid in water is a weak acid, but in liquid ammonia solvent is strong acid? 3. Solution: NH3 + H2O = NH4 + + OH -; Therefore, the bonding ability of NH3 and proton is stronger than that of H2O and proton. Because of this, the combination of acetic acid and water is weaker than that of acetic acid and ammonia. This is the familiar solvent flattening effect. 16-4 order the following substances in alkaline decreasing order and give an explanation. NH2OH NH3 N