聚合工艺对聚羧酸高性能的影响（The effect of polymerization process on high performance of polycarboxylate）.docVIP

聚合工艺对聚羧酸高性能的影响（The effect of polymerization process on high performance of polycarboxylate） In recent years, large engineering buildings such as Bridges, expressways and high-rise buildings have become increasingly demanding for concrete, and the demand for high performance concrete is increasing. As an important part of high performance concrete, polycarboxylic acid series high-performance water reducing agent is becoming more and more concerned. Series of poly (carboxylic acid high performance water reducing agent is polymer grafted copolymer, the current domestic manufacturers sprang up, and its production process, raw material type and foreign large difference, the quality of the product also has a large gap. For this purpose, the paper analyzes the domestic and foreign patents, and then systematically designs and experiments the polymerization process, and discusses the effects of different synthetic processes on the performance of polycarboxylic acid reducer. At present, the main monomer of the synthesis polycarboxylic acid series of high performance dewatering agent is methoxy polyethylene glycol (MPEG) and allyl polyethylene glycol (XPEG) etc. Synthesis process has many patents for its products both at home and abroad related introduction [1-2], synthesis methods about the following kinds: (1) one-time charging method: to a certain proportion of the reaction of monomer and initiator one-time join reactor, heating up to the specified temperature thermal reaction after a certain time, poly carboxylic acid neutralization reactant obtained water reducing agent products; (2) drops addition: mix reaction monomer mixture solution, mixture solution, at the same time the initiator were inserted in the dropping funnel according to certain speed drops to join a certain amount of water in the reactor, add finished, thermal reaction time, temperature and get water reducing agent products; (3) the reaction monomer is added in one time, the initiator solution is added or a