脉冲修复铅酸蓄电池硫化的基本原理（Basic principle of pulse repair lead-acid battery）.docVIP

脉冲修复铅酸蓄电池硫化的基本原理（Basic principle of pulse repair lead-acid battery） Basic principle of pulse repair lead-acid battery 1 what is battery vulcanization? White hard lead sulfate crystals are produced on the plates, which are very difficult to convert into active substances when they are charged. This is called sulfation. The causes of lead sulfate is placed for a long time over discharge or after discharge, lead sulfate particles dissolved in the electrolyte, the saturated state, the lead sulfate re crystallization at low temperature, and the crystalline lead sulfate is precipitated. In this way, the precipitated particles grow and develop again and again because of the temperature change, and the crystalline particles increase. The lead sulfate has poor conductivity, high resistance, low solubility and dissolution rate, and difficult to recover when charging. As a result of reduced capacity and shortened life expectancy. 2 what is the cause of the vulcanization? Normal lead-acid batteries lead to the formation of lead sulfate during discharge and are easily reduced to lead when charged. If the battery is not used and maintained properly, such as insufficient charge or excessive discharge, the anode will gradually form a thick, hard lead sulfate. This kind of lead sulfate is hard to be charged by conventional methods. The charging voltage is very high. Because of the poor charge acceptance ability, a large amount of gas is produced when charging. This phenomenon usually occurs in the negative pole, which is called irreversible sulfation. It causes the storage battery capacity to drop, even becomes the battery life to terminate the reason. It is generally believed that the reason for this irreversible sulfation is the recrystallization of lead sulfate, resulting in a decrease in solubility after the formation of coarse crystals The recrystallization of lead sulfate increases the crystal size because of the tendency of the polycrystalline system to decrease and its surfa