钙过硼酸钙的开发.doc

四川理工学院毕业论文 过硼酸钙的研制 学 生：王 晓 龙 学 号：09031010215 专 业：化学工程与工艺 班 级：2009级2班 指导老师：汤秀华 四川理工学院材料与化学工程学院 二〇一三年六月 摘要 本文研究了以硼砂和氢氧化钙为原料在不同质量配比和反应温度下，合成中间产物偏硼酸钙。在稳定剂作用下，以偏硼酸钙和30%的双氧水反应制备过硼酸钙，主要考察了反应温度、反应时间、液固比等因素对合成最终产物过硼酸钙的收率、活性氧含量的影响。研究结果表明：在硼砂/氢氧化钙=100：22和35℃下，更有利于合成偏硼酸钙；合成过硼酸钙的优化工艺条件为：反应温度为70℃，反应时间为40 min，反应液固比（mL/g）为4：1。 关键词：偏硼酸钙；过硼酸钙；活性氧；得率 Abstract In this paper, the borax and calcium hydroxide as raw materials in different quality ratios and reaction temperature,synthesis of intermediate product calcium metaborate was studied. Under the effect of stabilizers, calcium perborate was synthetised with calcium metaborate and hydrogen peroxide(30%). The effects of reaction temperature, reaction time, liquid-to-solid ratio on the synthesis of the final product of calcium perborate yield and active oxygen content was inspected mainly. The experimental results showed that: the borax/calcium hydroxide=100:22 and 35℃ was more conducived to the synthesis of calcium metaboratel;synthesis of calcium perborate to optimize process conditions as follows: reaction temperature was 70℃, the reaction time for 40 min,the liquid-to-solid ratio(mL/g) was 4:1. Key words ：Calcium metaborate；Calcium perborate；Active oxygen；Yield 目 录 TOC \o 1-3 \h \z \u HYPERLINK \l _Toc358470721 第一章 绪 论 PAGEREF _Toc358470721 \h 1 HYPERLINK \l _Toc358470722 1.1 引言 PAGEREF _Toc358470722 \h 1 HYPERLINK \l _Toc358470723 1.1.1 研究背景 PAGEREF _Toc358470723 \h 1 HYPERLINK \l _Toc358470724 1.1.2 研究意义 PAGEREF _Toc358470724 \h 1 HYPERLINK \l _Toc358470725 1.1.3 研究目的 PAGEREF _Toc358470725 \h 2 HYPERLINK \l _Toc358470726 1.2 过硼酸钙的简介 PAGEREF _Toc358470726 \h 2 HYPERLINK \l _Toc358470727 1.2.1 过硼酸钙的性质 PAGEREF _Toc358470727 \h 2 HYPERLINK \l _Toc358470728 1.2.2 过硼酸钙的应用 PAGEREF _Toc358470728 \h 3 HYPERLINK \l _Toc358470729 1.2.3 过硼酸钙的制备方法 PAGEREF _Toc358470729 \h 4 HYPERLINK \l _Toc358470730 第二章 实验部分 PAGEREF _Toc358470730 \h 5 HYPERLINK \l _Toc3584