XAFS技术在重金属界面吸附研究中的应用 - CiteSeerX.PDF

2008 14 5 ): 737~744 2008-10-25 应用与环境生物学报 ， ( Chin J Appl Environ Biol=ISSN 1006-687X DOI: 10.3724/SP.J.1145.2008.00737 XAFS技术在重金属界面吸附研究中的应用 * 方临川 黄巧云 蔡 鹏 梁 巍 (华中农业大学农业部亚热带农业资源与环境重点开放实验室 武汉 430070) 摘 要 X-射线吸收精细结构(XAFS)是同步辐射应用的最重要技术之一，可以在分子水平上研究重金属在天然颗粒 物、土壤、沉积物及生物等界面上吸附的微观结构，为深入阐明固相表面重金属结合机制提供实验证据 . 本文综述 了应用XAFS技术探讨矿物、腐殖质、植物组织和微生物等对重金属吸附机理的主要研究进展，并对XAFS技术在 多相体系对重金属的界面吸附、生物体对重金属的耐毒机理等方面的可能应用进行了展望，以期为环境重金属污 染的修复和治理提供基础资料 . 图4 表 1 参79 关键词 XAFS ；重金属；界面；吸附 CLC X171.5 Application of XAFS Technique in Interface Absorption of Heavy Metals * FANG Linchuan, HUANG Qiaoyun , CAI Peng LIANG Wei (Key Laboratory of Subtropical Agricultural Resources and Environment, Ministry of Agriculture, College of Resources and Environment, Huazhong Agriculture University, Wuhan 430070, China) Abstract X-ray absorption fine structure (XAFS) is one of the most important techniques for synchrotron radiation, and it can be used to study the adsorption mechanisms of heavy metals and their microscopic structures on natural particles, soils, sediments and organisms at molecular level, providing experimental evidences for elucidating the binding mechanisms of heavy metals on solid surfaces. In this paper, the advances in the application of the XAFS in the studies on the adsorption mechanisms of heavy metals on minerals, humic substances, plant tissues and microorganisms are reviewed, and the potential applications of the XAFS in the studies on the interfacial interactions of heavy metals in heterogeneous systems and the mechan