轻烧氧化镁对地质聚合物变形行为的影响及机理 - Ingenta Connect.PDF

40 11 1625 40 11 Vol. 40 No. 11 2 0 1 2 1 1 JOURNAL OF THE CHINESE CERAMIC SOCIETY November 2012 ( 210009) MgO (38 RH 95%) X MgO MgO MgO MgO MgO MgO [SiO ]4–[SiO ]4– 4 4 TQ172 A 0545–5648(2012)11–1625–06 2012–10–31 10:54:55 /kcms/detail/11.2310.TQ1054.201211.1625_014.html Effect of Light-burned Magnesium Oxide on Deformation Behavior of Geopolymer and its Mechanism LU Duyou ZHENG YanzengLIU Yongdao XU Zhongzi (College of Materials Science and Engineering, Nanjing University of Technology, Nanjing 210009, China) Abstract: For the exploration of a way to compensate the shrinkage of geopolymer, the deformation behavior of geopolymer bars with different contents of MgO was investigated via curing under different conditions (i.e., room temperature and 38 at relative humidity (RH) of 95%). The composition of the geopolymer was characterized by X-ray diffraction and thermogravimetry. The mechanism of MgO on affecting the deformation behaviour of geopolymer was proposed. The results show that the addition of MgO has an influence on the deformation behavior of geopolymer, and this effect is various with curing conditions. The addition of MgO decreases the shrinkage of geopolymer. The more MgO added, the less shrinkage would be. However, the effect of MgO in shrinkage compensation in geopolymer is not as significant as that in OPC system. MgO is involved in reactions in geopolymer based on dif- ferent mechanisms. MgO could bond with free [SiO ]4– to form magnesium silicate gel at a normal temperature, resulting in a hi