二氧化钛固载杂多酸光催化耦合降解酸性品红染料的研究 刘梅 施翔宇 .doc

二氧化钛固载杂多酸光催化耦合降解酸性品红染料的研究刘梅 施翔宇 赵景联 （西安交通大学环境工程系，西安 710049）摘要：研究二氧化钛固载杂多酸复相催化剂用于光催化降解酸性品红染料废水的特性和工艺，初步探讨了在此光催化系统中杂多酸和二氧化钛耦合的催化机理。在均相和固载的不同条件下的比较实验得出固载型杂多酸催化剂具有较高光降解效率。选取浸渍浓度、浸渍时间、烧结功率和烧结时间四个因素进行正交实验，得出催化剂的最佳制备条件：用0.06mol·L-1磷钨酸的水溶液浸渍二氧化钛28h，于120℃烘干，在微波炉750w功率下烧结50min。将此条件下制得的二氧化钛固载磷钨酸催化剂用于光催化耦合降解酸性品红溶液，在最优化反应条件下反应时间40min、固载型催化剂用量0.03g·L-1、光照距离17cm、pH值为5、酸性品红溶液初始浓度60mg·L-1、通气量100ml/s·L，酸性品红溶液的降解率可高达83.1%。 关键词：固载杂多酸；光催化；降解；酸性品红；二氧化钛Study on Photodegradation of Acid Fuchsine Catalyzed by Heteropolyacid Supported by Titanium Dioxide Liu Mei Shi Xiangyu Zhao Jinglian （Department of Environmental Engineering, Xi’an Jiaotong University, Xi’an 710049）Abstract: The characteristic and methodology of photocatalysis degradation on acid fusine assisted by TiO2-HPA (heteropolyacid) catalyst is studied, and the catalytic mechanism of the TiO2-HPA system is primarily discussed. The conclusion that supported HPA catalyst had higher photocatalysis degradation efficiency was arrived at from the different results in homogeneous solution compared with the experiment that HPA was supported on TiO2. The effects of the concentration of HPA solution and the time in impregnation, the power and the time in agglutination were researched, and from the orthogonal table, the optical preparation technology was gained: the concentration of H3PW12O40 is 0.06mol·L-1 and the time is 28h in impregnation, the power is 750W and the time is 50min in agglutination. The catalyst prepared mentioned above was used in photocatalysis degradation of acid fusine, when the doge is 0.03g·L-1, the distance of illumination is 17cm, pH＝5, the initial concentration of the acid fusine solution is below 60mg·L-1 and the air rate is 100ml/s·L , the degradation efficiency could come up to 83.1% after 40min. Key words: supported heteropolyacid, photocatalysis, degradation, acid fuchsine, titanium dioxide 染料废水因其组分复杂、有机物浓度高、难降解物质多、色度大、有毒等自身特点，以致其脱色与降解成为废水处理中的一大难题[1]。自1977年S.N.Frank和A.J.Bard首次报道了以悬浮的粉末TiO