环己烷对相变材料微胶囊结构与性能的影响 王学晨.pdfVIP

23 　4 　　　　　　　 Vol.23　No.4 　 2004 8 JOURNAL OF TIANJIN POLYTECHNIC UNIVERSITY August　2004 　 王学晨, 张兴祥, 樊耀峰, 牛建津, 蔡利海 ( , 300160) 　:将不同比例的环己烷添加到囊芯正十八烷中, 通过原位聚合法合成相变材料微 囊, 并采用SEM、DSC、TG 等测试方法对 囊性能进行研究.结果表明:随着环己烷添加量的增加, 经过热处理的微 囊的凹陷增大, 具有凹陷的 囊数增加, 微 囊的耐热温度也相应地增加;环己烷经过热处理挥发而产生的预留空间对 囊耐热性的提高起主要作用. :环己烷;微 囊;耐热性;相变材料;原位聚合 :O631.5;TS102.528 　　　:A　　　:1671-024X(2004)04-0006-05 Effects of cyclohexane on structures an properties of microcapsulate phase change materials WANG Xue-che , ZHANG Xi g-xia g, FAN Yao-fe g, NIU Jia -ji , CAI Li-hai (I stitute of Fu ctio al Fibers, Tia ji Polytech ic U iversity, Tia ji 300160, Chi a) Abstract:Microcapsulated phase cha ge material (MicroPCM)was produced by i -situ polymerizatio .The core material e - capsulated i the melami e-formaldehyde resi shell is a mixture of -octadeca e a d cyclohexa e.The microcap- sules properties are systematically studied through SEM, DSC a d TG.With the i crease of cyclohexa e, the surface of microcapsules tur s smoother, a d their dispersibility is improved.Additio ally, after microcapsules are heat- treated at 160 ℃for 30 mi utes, their co caves get larger a d the umber of the co cave capsules i crease as cyclo- hexa e i creasi g, a d their heat-resista ce temperatures are improved a d higher tha that of microcapsules without cyclohexa e.The reserved space that is made of cyclohexa e volatilizatio by heat-treati g has great effect o the im- proveme t of heat-resista ce temperature of microcapsules. Key wor s:cyclohexa e;microcapsules;heat-resista ce;phase cha ge material;i -situ polymerizati