电化学（Electrochemistry）.docVIP

电化学（Electrochemistry） Topic 06: electrochemical trap [thematic objectives]: 1, review and consolidate the relevant knowledge and basic principles of electrochemistry, and grasp some relevant laws of electrochemistry; 2 、 skilled use of relevant theoretical knowledge of electrochemistry to solve the relevant problems in life [classic questions] Type 1: application of galvanic cell principle in fuel cell [case 1]: someone designed the reaction of CH4 and O2 to form a primary cell with platinum electrode in KOH solution. The total response of the battery is similar to that of CH4 burning in O2, and the following statement is correct Each 1molCH4 can supply 8mole- to the external circuit The negative CH4 lost electrons, electrode reaction CH4+10OH-8e-=CO32-+7H2O The negative electrode is O2 and the electron is obtained. The electrode reaction is O2+2H2O+4e-=4OH- After the discharge of the battery, the solution PH increases continuously A., B., C., D. []: this inspiration is a specific application test of primary battery principle in a fuel cell, first to determine the polarity of the batteries, the method is to determine the occurrence of the electrode is electronic or electronic reaction, if there is loss of electronic reaction is the original battery anode and cathode is. CH4 is similar to CH4 in the O2 combustion reaction on platinum electrode, namely CH4, CO2 strictly generated CO2 also reacts with KOH to form K2CO3, valence increases, lost electrons, is the cathode of the battery, the electrode reaction is CH4-8e-+10OH-=CO32-+7H2O, 1molCH4 in 8mole- shift reaction, O2 reaction, the positive gain electron electrode reaction is O2+2H2O+4e-=4OH-. Although the positive electrode produces OH-, the negative electrode consumes OH-, but from the total reaction CH4+2O2+2KOH=K2CO3+3H2O, it can be seen that the KOH is consumed, so the pH value of the solution drops continuously when the battery is discharged. Answer: A Comment: fuel cell occurred in the specific conditions of