硬化水泥净浆基于纳米压痕的相态识别及水化程度计算.pdfVIP

《复合材料学报》 Jan. 15 2017 Vol.34 No.x: xxx-xxx Acta Materiae Compositae Sinica ISSN 1000-3851 CN 11-1801/TB DOI ： 10.13801/ki.fhclxb007 硬化水泥净浆基于纳米压痕的相态识别与水化程度计算 * 魏 亚, 高 翔，梁思明 (清华大学 土木工程系 土木工程安全与耐久教育部重点实验室，北京 100084) 摘 要：采用纳米原位压痕手段量测了硬化水泥净浆中单一相态的代表性微观力学性质，并采用纳米点阵 压痕研究了各相态的含量。研究对象囊括了水灰比 0.3、0.4、0.5 的纯水泥净浆，以及水灰比为 0.3 情况下 含 50%、70%矿渣掺量复合体系，共 5 种配比，以表征它们的相态分布与微观力学性质的异同点。掺矿渣的 试件中含有明显多的复合相，因此提出三相模型测算复合相中未水化物的体积分数。此外，提出了基于纳 米压痕技术计算纯水泥和掺矿渣试件水化程度的方法，结果吻合于热重分析的结果，其中纯水泥净浆中复 合相较少，计算得到的水化程度优于针对掺矿渣试件的计算。 关键词：硬化水泥净浆；纳米压痕；微观力学性质；水化程度；三相模型 中图分类号：TB321 文献标志码：A Nanoindentation-based study of the microstructure and degree of hydration in hardened cement pastes WEI Ya*, GAO Xiang, LIANG Siming (Key Laboratory of Civil Engineering Safety and Durability of China Education Ministry, Department of Civil Engineering, Tsinghua University, Beijing 100084, China) Abstract: The nanoindentation technique was used to measure the micro-mechanical properties of single phase in hardened cement pastes through discrete nanoindentation, and the properties over large areas through grid nanoin- dentation. Comparisons were made between pastes with water-to-cementitious materials (w/cm) ratio by mass of 0.3, 0.4, and 0.5 and the slag content of 0, 50, and 70 % for w/cm=0.3 paste, to illustrate their differences on the phase distribution and the micro-mechanical properties. Significant portion of composite phase was found in slag-blended paste. A three-phase model was used to determine the volume fraction of the unhydrated phase inclu