文献汇报 江山 150422.pptxVIP

文献汇报;Scheme 1. The construction and operating principle of the UCNPs-ZnPc nanophotosensitizer.;Fig. 1. TEM image of NaYF4:Yb3+, Er3+ UCNPs (a) before phase transfer and (b) after phase transfer.;Fig. 2. FTIR transmission spectra of amino-functionalized NaYF4:Yb3+, Er3+ UCNPs (black curve), ZnPc (COOH)4 (blue curve) and UCNPs-ZnPc nanoconjugates (green curve). (For interpretation of the references to color in this figure legend, the reader is referred to the web version of this article.);Fig. 3. (a) UV-Vis absorption spectra of UCNPs nanoconjugates covalently bounded with different concentration of ZnPc(COOH)4. The weight percentage of ZnPc (COOH)4 per UCNPs nanoconjugates is also given. (b) Consumption of DPBF over time with 980 nm irradiation due to 1O2 generation from different weight percentage of ZnPc(COOH)4 per UCNPs nanoconjugates constructed in the covalent way. (c) Change of the absorption intensities of ZnPc with increasing the amount of added ZnPc non-convalently absorbed to UCPNs. The inset shows U-VIS absorption spectra of UCNPs non-covalently absorbed with ZnPc at different added values. (d) Consumption of DPBF over time due to 1O2 generation for different weight percentage of non-convalently absorbed ZnPc with the same power density 980 nm irradiation.;Fig. 4. Absorption spectra of eluate after washing with DMF 1, 2, and 3 times the physically adsorbed UCNPs-ZnPc complexes (solid lines), and corresponding absorption spectra of the eluate the for covalently bonded UCNPs-ZnPc/FA nanoconjugates are shown in inset (dashed lines).;Fig. 5. (a) Upconversion luminescence spectrum of UCNPs (black curve) as donor and the absorption spectrum of the acceptor ZnPc(COOH)4 (blue curve) as acceptor. (b)Upconversion luminescence spectra of UCNPs (black curve) and UCNPs-ZnPc/FA conjugates (green curve) under excitation of 980 nm. Photographs of (c) UCNPs and (d) UCNPs-ZnPc/FA nanoconjugates under ambient light (left) and under 980 nm laser irradiation (right), respectiv