油的酸价（The acid value of oil）.doc

油的酸价（The acid value of oil） 1. Sensitivity of titration endpoint indication In the determination of acid price by titration method, the accuracy and accuracy of determination of titration endpoint is the key to the accuracy and accuracy of this method. In gb5009.37-85 [33], the phenolphthalein indicator is used, but it is often affected by some undesirable phenomena in the oil color and titration reaction, which makes the phenolphthalein indicator less sensitive. In operation, it is not easy to identify and master, even larger errors, to reduce the error of judgment. The following measures can be taken: 1.1 oil samples with darker colors (such as peanut oil) On the premise of guarantee test accuracy, decrease the dosage of sample, at the same time increase the appropriate solvent dosage, to dilute the sample pigment to the indicator of titration end point interference, facilitates observation of the finish. The turbidity of the titration reaction Sample solution turbidity in titration reaction phenomenon: is the major reason for the excessive dosage of alkali in the process of titration, at the same time will also generate some of the water in the titration reaction, so that the proportion of the water in the sample solution system is too big, relative to reduce the amount of ethanol, make sample and alkaline facies cannot miscibility, and oscillation in the titration of emulsification, plus most of the soap in a lot of water can be generated by neutralization reaction precipitation, then increase the sample solution turbidity phenomena in the titration reaction, seriously affect the judgment of color changes of titration end point. Therefore, once the turbidity occurs in titration, it can be added by 95% of the neutral ethanol in the sample solution to form a homogenous liquid-phase system. At the same time, it is necessary to prevent large quantities of water from being brought into the sample mixture before titration. 1.2.1 the containers and other utensils shoul